亚乙基二胺铜溶液

  • 基本信息
  • 物化性质
  • 安全信息
  • 毒理性
  • MSDS
  • 结构与计算化学

亚乙基二胺铜溶液 基本信息

中文名称:
亚乙基二胺铜溶液 
中文别名:
双氢氧化乙二胺铜(II);
亚乙基二胺铜络合物;
氢氧化双(乙二胺)铜;
双氢氧化乙二胺铜 
英文名称:
Copper(2+),bis(1,2-ethanediamine-kN1,kN2)-, hydroxide (1:2), (SP-4-1)-
英文别名:
CUPRIETHYLENEDIAMINE;
Bis(ethylenediamine)copper(II) hydroxide;
Copper ethylenediamine;
CUPRIETHYLENEDIAMINE SOLUTION;
Copper(II)-ethylenediamine complex;
Copper(II)-ethylenediame complex;
Cupriethylenediamine dihydroxide 
CAS No.:
14552-35-3
分 子 式:
C4H16CuN4.2HO
分 子 量:
121.63
精确分子量:
120.98300
PSA:
24.06000
MDL:
MFCD00274628
EINECS:
238-597-7
InChI:
The Key: WATCRQGYOIZIHC-UHFFFAOYSA-L
风险术语:
R34
安全术语:
S26S45S36/S37/S39
分子结构式:
SDS:
查看

亚乙基二胺铜溶液 物化性质

密度:
1.086 g/mL at 25 °C
沸点:
119.7ºC at 760mmHg
闪点:
33.9ºC
其它信息:

1.       性状:深蓝色液体

2.       密度(g/mL,25/4):1.086

3.       相对蒸汽密度(g/mL,空气=1):未确定

4.       熔点(ºC):未确定

5.       沸点(ºC,常压):未确定

6.       沸点(ºC,5.2kPa):未确定

7.       折射率:未确定

8.       闪点(ºC):未确定

9.       比旋光度º):未确定

10.    自燃点或引燃温度(ºC):未确定

11.    蒸气压(kPa,25ºC):未确定

12.    饱和蒸气压(kPa,60ºC):未确定

13.    燃烧热(KJ/mol):未确定

14.    临界温度(ºC):未确定

15.    临界压力(KPa):未确定

16.    油水(辛醇/水)分配系数的对数值:未确定

17.    爆炸上限(%,V/V):未确定

18.    爆炸下限(%,V/V):未确定

19.    溶解性:未确定

亚乙基二胺铜溶液 安全信息

危险类别码:
34
安全说明:
26-36/37/39-45
安全标志:
S26:万一接触眼睛,立即使用大量清水冲洗并送医诊治。
S45:出现意外或者感到不适,立刻到医生那里寻求帮助(最好带去产品容器标签)。
:
危险标志:
C: Corrosive;

亚乙基二胺铜溶液 毒理性

毒理学数据:

1、急性毒性:主要的刺激性影响:

在皮肤上面:刺激皮肤和粘膜;

   在眼睛上面:刺激的影响。

亚乙基二胺铜溶液 MSDS

Name: Copper(II)-Ethylenediamine Complex for Viscosity Determination of Material Safety Data Sheet
Synonym: None
CAS: 14552-35-3
Section 1 - Chemical Product   MSDS Name:Copper(II)-Ethylenediamine Complex for Viscosity Determination of Material Safety Data Sheet
Synonym:None

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
14552-35-3 COPPER(II)-ETHYLENEDIAMINE 100 238-597-7
Hazard Symbols: C
Risk Phrases: 34

Section 3 - HAZARDS IDENTIFICATION
  EMERGENCY OVERVIEW
Causes burns.Corrosive.
Potential Health Effects
Eye:
Contact with eyes may cause severe irritation, and possible eye burns.
Skin:
Causes skin burns.
Ingestion:
May cause severe and permanent damage to the digestive tract. Causes gastrointestinal tract burns.
Inhalation:
May cause severe irritation of the respiratory tract with sore throat, coughing, shortness of breath and delayed lung edema. Causes chemical burns to the respiratory tract.
Chronic:
None

Section 4 - FIRST AID MEASURES
  Eyes: Get medical aid immediately. Do NOT allow victim to rub eyes or keep eyes closed. Extensive irrigation with water is required (at least 30 minutes).
Skin:
Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Destroy contaminated shoes.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Do NOT use mouth-to-mouth resuscitation.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
  General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.
Extinguishing Media:
In case of fire, use water, dry chemical, chemical foam, or alcohol-resistant foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
  General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Clean up spills immediately, observing precautions in the Protective Equipment section. Avoid generating dusty conditions. Provide ventilation.

Section 7 - HANDLING and STORAGE
  Handling:
Keep container tightly closed. Do not get on skin or in eyes. Do not ingest or inhale. Use with adequate ventilation. Discard contaminated shoes.
Storage:
Keep container closed when not in use. Store in a cool, dry, well-ventilated area away from incompatible substances. Corrosives area.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
  Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 14552-35-3: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to minimize contact with skin.
Respirators:
A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use. Wear a NIOSH/MSHA or European Standard EN 149 approved full-facepiece airline respirator in the positive pressure mode with emergency escape provisions.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
 
Physical State: Solid
Color: clear dark blue
Odor: None reported.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: N/A
Explosion Limits, upper: N/A
Decomposition Temperature:
Solubility in water: soluble in water
Specific Gravity/Density: 1.1000g/cm3
Molecular Formula: C2Cu2H8N2-n
Molecular Weight: 159.148

Section 10 - STABILITY AND REACTIVITY
  Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Excess heat, oxidizers.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, carbon dioxide, nitrogen.
Hazardous Polymerization: Has not been reported.

Section 11 - TOXICOLOGICAL INFORMATION
  RTECS#:
CAS# 14552-35-3 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
COPPER(II)-ETHYLENEDIAMINE - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION
 

Section 13 - DISPOSAL CONSIDERATIONS
  Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION
 
IATA
Shipping Name: CUPRIETHYLENEDIAMINE SOLUTION
Hazard Class: 8 (6.1)
UN Number: 1761
Packing Group: II
IMO
Shipping Name: CUPRIETHYLENEDIAMINE SOLUTION
Hazard Class: 8 (6.1)
UN Number: 1761
Packing Group: II
RID/ADR
Shipping Name: CUPRIETHYLENEDIAMINE SOLUTION
Hazard Class: 8
UN Number: 1761
Packing group: II

Section 15 - REGULATORY INFORMATION
 
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 34 Causes burns.
Safety Phrases:
S 25 Avoid contact with eyes.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 14552-35-3: No information available.
Canada
CAS# 14552-35-3 is listed on Canada's NDSL List.
CAS# 14552-35-3 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 14552-35-3 is listed on the TSCA inventory.


SECTION 16 - ADDITIONAL INFORMATION
N/A

亚乙基二胺铜溶液 分子结构与计算化学数据

分子结构数据

1、摩尔折射率:无可用的

2、摩尔体积(cm3/mol):无可用的

3、等张比容(90.2K):无可用的

4、表面张力(dyne/cm):无可用的

5、介电常数:无可用的

6、极化率(10-24cm3):无可用的

7、单一同位素质量:120.982699 Da

8、标称质量:121 Da

9、平均质量:121.6284 Da

计算化学数据

1.疏水参数计算参考值(XlogP):无

2.氢键供体数量:6

3.氢键受体数量:6

4.可旋转化学键数量:2

5.互变异构体数量:无

6.拓扑分子极性表面积106

7.重原子数量:11

8.表面电荷:0

9.复杂度:6

10.同位素原子数量:0

11.确定原子立构中心数量:0

12.不确定原子立构中心数量:0

13.确定化学键立构中心数量:0

14.不确定化学键立构中心数量:0

15.共价键单元数量:5

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