α,β-二氯丙烯腈

  • 基本信息
  • 物化性质
  • 安全信息
  • 毒理性
  • MSDS
  • 海关数据
  • 结构与计算化学
  • 上游产品

α,β-二氯丙烯腈 基本信息

中文名称:
α,β-二氯丙烯腈 
中文别名:
Alpha,Β-二氯丙烯腈;
α,β-二氯丙烯腈 
英文名称:
2-Propenenitrile,2,3-dichloro-
英文别名:
(Z)-2,3-dichloroprop-2-enenitrile;
sGXDBHbqBSKSpQH;
EINECS 244-964-2;
2,3-Dichloroacrylonitrile;
TL 236;
ACRYLONITRILE,2,3-DICHLORO;
2-Propenenitrile,2,3-dichloro 
CAS No.:
22410-58-8
分 子 式:

C3HCl2N

分 子 量:
121.96
精确分子量:
120.94900
PSA:
23.79000
MDL:
MFCD00800970
EINECS:
244-964-2
InChI:
The Key: NDWDVOQVCRKCDJ-UHFFFAOYSA-N
危险品标志:

 

风险术语:

R11R40R23/24/25R36/37/38

安全术语:

S16S26S45S36/S37/S39

分子结构式:
SDS:
查看

α,β-二氯丙烯腈 物化性质

密度:
1.391g/cm3
沸点:
129.5ºC at 760mmHg
闪点:
36.2ºC
折射率:
1.484-1.486
蒸汽压:
10.1mmHg at 25°C
存储条件/存储方法:

 

 密闭于阴凉干燥环境中

稳定性相关:

 

遵照规定使用和储存则不会分解。

其它信息:

1.       性状:无可用

2.       密度(g/mL,25/4):无可用

3.       相对蒸汽密度(g/mL,空气=1):无可用

4.       熔点(ºC):无可用

5.       沸点(ºC,常压):50-52/50mmHg

6.       沸点(ºC,5.2kPa):无可用

7.       折射率:1.484-1.486

8.       闪点(ºC):无可用

9.       比旋光度(º):无可用

10.    自燃点或引燃温度(ºC):无可用

11.    蒸气压(kPa,25ºC):无可用

12.    饱和蒸气压(kPa,60ºC):无可用

13.    燃烧热(KJ/mol):无可用

14.    临界温度(ºC):无可用

15.    临界压力(KPa):无可用

16.    油水(辛醇/水)分配系数的对数值:无可用

17.    爆炸上限(%,V/V):无可用

18.    爆炸下限(%,V/V):无可用

19.    溶解性:无可用

α,β-二氯丙烯腈 安全信息

海关代码:
2926909090
危险类别码:
40-36/37/38-23/24/25-11
安全说明:
45-36/37/39-26-16
安全标志:
S16:远离火源。
S26:万一接触眼睛,立即使用大量清水冲洗并送医诊治。
S45:出现意外或者感到不适,立刻到医生那里寻求帮助(最好带去产品容器标签)。
:
危险标志:
T,F

α,β-二氯丙烯腈 毒理性

CHEMICAL IDENTIFICATION

RTECS NUMBER :
AT5950000
CHEMICAL NAME :
Acrylonitrile, 2,3-dichloro-
CAS REGISTRY NUMBER :
22410-58-8
LAST UPDATED :
199012
DATA ITEMS CITED :
1
MOLECULAR FORMULA :
C3-H-Cl2-N
MOLECULAR WEIGHT :
121.95
WISWESSER LINE NOTATION :
NCYGU1G

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LCLo - Lowest published lethal concentration
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
910 mg/m3/10M
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
NDRC** National Defense Research Committee, Office of Scientific Research and Development, Progress Report. Volume(issue)/page/year: NDCrc-132,JUN1942
生态数据:

 

该物质对环境可能有危害,对水体应给予特别注意。

α,β-二氯丙烯腈 MSDS

Name: alpha,beta-Dichloroacrylonitrile, 98% Material Safety Data Sheet
Synonym: 2,3-Dichloro-2-propenenitrile; 2,3-Dichloroacrylonitrile.
CAS: 22410-58-8
Section 1 - Chemical Product MSDS Name: alpha,beta-Dichloroacrylonitrile, 98% Material Safety Data Sheet
Synonym: 2,3-Dichloro-2-propenenitrile; 2,3-Dichloroacrylonitrile.
SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
22410-58-8 alpha,beta-Dichloroacrylonitrile 98 244-964-2
Hazard Symbols: XI
Risk Phrases: 36/37/38
SECTION 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW Irritating to eyes, respiratory system and skin.The toxicological properties of this material have not been fully investigated. Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and diarrhea. The toxicological properties of this substance have not been fully investigated. Metabolism may release cyanide, which may result in headache, dizziness, weakness, collapse, unconsciousness and possible death.
Inhalation:
Causes respiratory tract irritation. May be metabolized to cyanide which in turns act by inhibiting cytochrome oxidase impairing cellular respiration.
Chronic:
No information found.
SECTION 4 - FIRST AID MEASURES
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:


SECTION 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Vapors may be heavier than air. They can spread along the ground and collect in low or confined areas.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or appropriate foam.
SECTION 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Clean up spills immediately, observing precautions in the Protective Equipment section. Remove all sources of ignition. Provide ventilation.
SECTION 7 - HANDLING and STORAGE
Handling:
Wash thoroughly after handling. Ground and bond containers when transferring material. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames. Use only with adequate ventilation. Keep away from heat, sparks and flame. Pure vapor will be uninhibited and may polymerize in vents or other confined spaces.
Storage:
Keep away from sources of ignition. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.
SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use process enclosure, local exhaust ventilation, or other engineering controls to control airborne levels. Exposure Limits CAS# 22410-58-8: Personal Protective Equipment
Eyes:
Wear chemical splash goggles.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use.
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Liquid
Color: clear, colorless to pale yellow
Odor: Irritating odor
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 50-52 deg C @ 50 mm Hg
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: 20 deg C ( 68.00 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C3HCl2N
Molecular Weight: 121.96
SECTION 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Light, ignition sources, excess heat, confined spaces.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Hydrogen chloride, hydrogen cyanide, carbon monoxide, oxides of nitrogen, carbon dioxide.
Hazardous Polymerization: May occur.
SECTION 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 22410-58-8: AT5950000
LD50/LC50:
Not available.
Inhalation LCLo mouse: 910 mg/m3/10M.
Carcinogenicity:
alpha,beta-Dichloroacrylonitrile - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
SECTION 12 - ECOLOGICAL INFORMATION
SECTION 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations.
SECTION 14 - TRANSPORT INFORMATION IATA Not regulated as a hazardous material. IMO Not regulated as a hazardous material. RID/ADR Not regulated as a hazardous material.
SECTION 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives
Hazard Symbols: XI
Risk Phrases:
R 36/37/38 Irritating to eyes, respiratory system and skin.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S 37/39 Wear suitable gloves and eye/face protection. WGK (Water Danger/Protection) CAS# 22410-58-8: No information available. Canada None of the chemicals in this product are listed on the DSL/NDSL list. CAS# 22410-58-8 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 22410-58-8 is not listed on the TSCA inventory. It is for research and development use only.
SECTION 16 - ADDITIONAL INFORMATION
MSDS Creation Date: 2/08/1999 Revision #3 Date: 10/21/2003 The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no way shall the company be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if the company has been advised of the possibility of such damages.

SECTION 16 - ADDITIONAL INFORMATION
N/A

α,β-二氯丙烯腈 海关数据

中国海关编码:2926909090

概述:
2926909090 其他腈基化合物. 增值税率:17.0% 退税率:9.0% 监管条件:无 最惠国关税:6.5% 普通关税:30.0%
申报要素:
品名, 成分含量, 用途
摘要/Summary:
HS:2926909090 other nitrile-function compounds VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

α,β-二氯丙烯腈 分子结构与计算化学数据

分子结构数据

1   摩尔折射率:25.46

2   摩尔体积m3/mol87.6

3   等张比容(90.2K):220.0

4   表面张力dyne/cm39.7

5   极化率10-24cm310.09

计算化学数据

1.疏水参数计算参考值(XlogP):1.7

2.氢键供体数量:0

3.氢键受体数量:1

4.可旋转化学键数量:0

5.互变异构体数量:无

6.拓扑分子极性表面积23.8

7.重原子数量:6

8.表面电荷:0

9.复杂度:107

10.同位素原子数量:0

11.确定原子立构中心数量:0

12.不确定原子立构中心数量:0

13.确定化学键立构中心数量:1

14.不确定化学键立构中心数量:0

15.共价键单元数量:1

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