三甲基(苯基硒代甲基)硅烷

  • 基本信息
  • 物化性质
  • 安全信息
  • 毒理性
  • MSDS
  • 结构与计算化学
  • 上游产品
  • 下游产品

三甲基(苯基硒代甲基)硅烷 基本信息

中文名称:
三甲基(苯基硒代甲基)硅烷 
中文别名:
三甲基(苯基硒代甲基)硅烷;
(苯基锡甲基)三甲基硅烷 
英文名称:
Benzene,[[(trimethylsilyl)methyl]seleno]-
英文别名:
trimethyl(phenylselanylmethyl)silane;
Phenylselenomethyltrimethylsilan;
Phenylselenotrimethylsilylmethane;
Trimethyl(phenylselenomethyl)silane;
(Phenylselenomethyl)trimethylsilane;
EINECS 260-077-3 
CAS No.:
56253-60-2
分 子 式:
C10H16SeSi
分 子 量:
243.28
精确分子量:
244.01900
PSA:
0.00000
MDL:
MFCD00042834
EINECS:
260-077-3
BRN:
1932376
InChI:
The Key: QXFASNHOOXGHDD-UHFFFAOYSA-N
危险品标志:
N
风险术语:
R33R23/25R50/53
安全术语:
S28S45S60S61
分子结构式:
SDS:
查看

三甲基(苯基硒代甲基)硅烷 物化性质

外观与性状:
黄色-绿色液体
密度:
1.176 g/mL at 25ºC(lit.)
沸点:
106ºC6 mm Hg(lit.)
闪点:
>230 °F
折射率:
n20/D 1.552(lit.)
存储条件/存储方法:

 

保持贮藏器密封

放入紧密的贮藏器内,储存在阴凉,干燥的地方

稳定性相关:

 

遵照规定使用和储存则不会分解。

其它信息:

1.       性状:黄绿色液体

2.       密度(g/mL,25/4):1.176

3.       相对蒸汽密度(g/mL,空气=1):无可用

4.       熔点(ºC):无可用

5.       沸点(ºC,常压):106

6.       沸点(ºC,5.2kPa):无可用

7.       折射率:无可用

8.       闪点(ºC):95

9.       比旋光度(º):无可用

10.    自燃点或引燃温度(ºC):无可用

11.    蒸气压(kPa,25ºC):无可用

12.    饱和蒸气压(kPa,60ºC):无可用

13.    燃烧热(KJ/mol):无可用

14.    临界温度(ºC):无可用

15.    临界压力(KPa):无可用

16.    油水(辛醇/水)分配系数的对数值:无可用

17.    爆炸上限(%,V/V):无可用

18.    爆炸下限(%,V/V):无可用

19.    溶解性:无可用

三甲基(苯基硒代甲基)硅烷 安全信息

包装等级:
III
风险类别:
6.1(b)
危险类别码:
23/25-33-50/53
安全说明:
20/21-28-45-60-61
安全标志:
S28:接触皮肤之后,立即使用大量皂液洗涤。
S45:出现意外或者感到不适,立刻到医生那里寻求帮助(最好带去产品容器标签)。
S60:本物质残余物和容器必须作为危险废物处理。
S61:避免排放到环境中。参考专门的说明/安全数据表。
危险标志:
T,N

三甲基(苯基硒代甲基)硅烷 毒理性

生态数据:

 

该物质对环境可能有危害,对水体应给予特别注意。

三甲基(苯基硒代甲基)硅烷 MSDS

    Version 1.2
    Regulation (EC) No 1907/2006

    1 - Product and Company Information

    Product Name        (PHENYLSELENOMETHYL)TRIMETHYLSILANE, 99%    

    2 - Hazards Identification

    SPECIAL INDICATION OF HAZARDS TO HUMANS AND THE ENVIRONMENT
    Toxic by inhalation and if swallowed. Danger of cumulative
    effects. Very toxic to aquatic organisms, may cause long-term
    adverse effects in the aquatic environment.

    3 - Composition/Information on Ingredients

    Product Name        CAS #        EC no        Annex I    
    Index Number
    (PHENYLSELENOMETHYL)TRIMETHYLSILAN 56253-60-2 260-077-3 034-002-00-8
    E
    Formula        C10H16SeSi    
    Molecular Weight 243,2900 AMU

    4 - First Aid Measures

    AFTER INHALATION
    If inhaled, remove to fresh air. If not breathing give
    artificial respiration. If breathing is difficult, give oxygen.
    AFTER SKIN CONTACT
    In case of contact, immediately wash skin with soap and copious
    amounts of water.
    AFTER EYE CONTACT
    In case of contact, immediately flush eyes with copious amounts
    of water for at least 15 minutes.
    AFTER INGESTION
    If swallowed, wash out mouth with water provided person is
    conscious. Call a physician.

    5 - Fire Fighting Measures
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    EXTINGUISHING MEDIA
    Suitable: Water spray. Carbon dioxide, dry chemical powder, or
    appropriate foam.
    SPECIAL RISKS
    Specific Hazard(s): Emits toxic fumes under fire conditions.
    SPECIAL PROTECTIVE EQUIPMENT FOR FIREFIGHTERS
    Wear self-contained breathing apparatus and protective clothing
    to prevent contact with skin and eyes.

    6 - Accidental Release Measures

    PROCEDURE(S) OF PERSONAL PRECAUTION(S)
    Wear respirator, chemical safety goggles, rubber boots, and
    heavy rubber gloves.
    METHODS FOR CLEANING UP
    Cover with dry lime or soda ash, pick up, keep in a closed
    container, and hold for waste disposal. Ventilate area and wash
    spill site after material pickup is complete.

    7 - Handling and Storage

    HANDLING
    Directions for Safe Handling: Do not breathe vapor. Avoid
    contact with eyes, skin, and clothing.
    STORAGE
    Conditions of Storage: Keep tightly closed. Store in a cool dry
    place.

    8 - Exposure Controls / Personal Protection

    ENGINEERING CONTROLS
    Safety shower and eye bath. Mechanical exhaust required.
    GENERAL HYGIENE MEASURES
    Wash thoroughly after handling. Wash contaminated clothing before
    reuse.
    PERSONAL PROTECTIVE EQUIPMENT
    Respiratory Protection: Use respirators and components tested and
    approved under appropriate government standards such as NIOSH (US)
    or CEN (EU). Where risk assessment shows air-purifying respirators
    are appropriate use a full-face respirator with multi-purpose
    combination (US) or type ABEK (EN 14387) respirator cartridges as
    a backup to engineering controls. If the respirator is the sole
    means of protection, use a full-face supplied air respirator.
    Hand Protection: Compatible chemical-resistant gloves.
    Eye Protection: Chemical safety goggles.

    9 - Physical and Chemical Properties

    Appearance        Color: Deep yellow-green    
    Form: Clear liquid
    Property        Value        At Temperature or Pressure    
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    pH N/A
    BP/BP Range        106,000 °C        6,000 mmHg    
    MP/MP Range        N/A    
    Flash Point        95,000 °C        Method: closed cup    
    Flammability        N/A    
    Autoignition Temp        N/A    
    Oxidizing Properties N/A
    Explosive Properties N/A
    Explosion Limits        N/A    
    Vapor Pressure        N/A    
    SG/Density        1,1760 g/cm3    
    Partition Coefficient N/A
    Viscosity        N/A    
    Vapor Density        N/A    
    Saturated Vapor Conc. N/A
    Evaporation Rate        N/A    
    Bulk Density        N/A    
    Decomposition Temp.        N/A    
    Solvent Content        N/A    
    Water Content        N/A    
    Surface Tension        N/A    
    Conductivity        N/A    
    Miscellaneous Data        N/A    
    Solubility        N/A    

    10 - Stability and Reactivity

    STABILITY
    Materials to Avoid: Strong oxidizing agents.
    HAZARDOUS DECOMPOSITION PRODUCTS
    Hazardous Decomposition Products: Carbon monoxide, Carbon dioxide,
    Silicon oxide, Selenium/selenium oxides.

    11 - Toxicological Information

    SIGNS AND SYMPTOMS OF EXPOSURE
    To the best of our knowledge, the chemical, physical, and
    toxicological properties have not been thoroughly investigated.
    ROUTE OF EXPOSURE
    Multiple Routes: May be harmful by inhalation, ingestion, or
    skin absorption. May cause irritation.
    TARGET ORGAN INFORMATION
    Liver.

    12 - Ecological Information

    No data available.

    13 - Disposal Considerations

    SUBSTANCE DISPOSAL
    Dissolve or mix the material with a combustible solvent and burn
    in a chemical incinerator equipped with an afterburner and
    scrubber. Observe all federal, state, and local environmental
    regulations.

    14 - Transport Information
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    RID/ADR
    UN#: 2810
    Class: 6.1
    PG: III
    Proper Shipping Name: Toxic liquid, organic, n.o.s.
    IMDG
    UN#: 2810
    Class: 6.1
    PG: III
    Proper Shipping Name: Toxic liquid, organic, n.o.s.
    Marine Pollutant: No
    Severe Marine Pollutant: No
    Technical Name: Required
    IATA
    UN#: 2810
    Class: 6.1
    PG: III
    Proper Shipping Name: Toxic liquid, organic, n.o.s.
    Inhalation Packing Group I: No
    Technical Name: Required

    15 - Regulatory Information

    CLASSIFICATION AND LABELING ACCORDING TO EU DIRECTIVES
    ANNEX I INDEX NUMBER: 034-002-00-8
    NOTA: A
    INDICATION OF DANGER: T-N
    Toxic. Dangerous for the environment.
    R-PHRASES: 23/25-33-50/53
    Toxic by inhalation and if swallowed. Danger of cumulative
    effects. Very toxic to aquatic organisms, may cause long-term
    adverse effects in the aquatic environment.
    S-PHRASES: 20/21-28-45-60-61
    When using do not eat, drink, or smoke. After contact with
    skin, wash immediately with plenty of soap-suds. In case of
    accident or if you feel unwell, seek medical advice immediately
    (show the label where possible). This material and its
    container must be disposed of as hazardous waste. Avoid release
    to the environment. Refer to special instructions/safety data
    sheets.
    COUNTRY SPECIFIC INFORMATION
    Germany
    WGK: 3
    Self-Classification

    16 - Other Information

    WARRANTY
    The above information is believed to be correct but does not
    purport to be all inclusive and shall be used only as a guide. The
    information in this document is based on the present state of our
    knowledge and is applicable to the product with regard to
    appropriate safety precautions. It does not represent any
    guarantee of the properties of the product. Inc.,
    shall not be held liable for any damage resulting from handling or
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    from contact with the above product. See reverse side of invoice
    or packing slip for additional terms and conditions of sale.
    Copyright 2010 Co. License granted to make
    unlimitedpaper copies for internal use only.
    DISCLAIMER
    For R&D use only. Not for drug, household or other uses.
    ALDRICH        www.molbase.com    


SECTION 16 - ADDITIONAL INFORMATION
N/A

三甲基(苯基硒代甲基)硅烷 分子结构与计算化学数据

计算化学数据

1、   疏水参数计算参考值(XlogP):无可用

2、   氢键供体数量:0

3、   氢键受体数量:0

4、   可旋转化学键数量:3

5、   拓扑分子极性表面积(TPSA):0

6、   重原子数量:12

7、   表面电荷:0

8、   复杂度:122

9、   同位素原子数量:0

10、   确定原子立构中心数量:0

11、   不确定原子立构中心数量:0

12、   确定化学键立构中心数量:0

13、   不确定化学键立构中心数量:0

14、   共价键单元数量:1

三甲基(苯基硒代甲基)硅烷 上游产品

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