1,2,3,4-环戊四羧酸二酐

  • 基本信息
  • 物化性质
  • 安全信息
  • 毒理性
  • MSDS
  • 海关数据
  • 结构与计算化学
  • 表征图谱

1,2,3,4-环戊四羧酸二酐 基本信息

中文名称:
1,2,3,4-环戊四羧酸二酐 
中文别名:
1,2,3,4-环戊四羧酸二酐;
1,2,3,4-环戊烷四羧酸二酐 
英文名称:
1H-Cyclopenta[1,2-c:3,4-c']difuran-1,3,4,6(3aH)-tetrone,tetrahydro-
英文别名:
1,2,3,4-Cyclopentanetetracarboxylic Dianhydride;
1,2,3,4-CYCLOPENTANETETRACARBOXYLIC DIANHYDRIDE 
CAS No.:
6053-68-5
分 子 式:
C9H6O6
分 子 量:
210.14
精确分子量:
210.01600
PSA:
86.74000
EINECS:
227-964-7
InChI:
The Key: NLWBEORDOPDUPM-TXICZTDVSA-N
风险术语:
R36/37
安全术语:
S25
分子结构式:
SDS:
查看

1,2,3,4-环戊四羧酸二酐 物化性质

密度:
1.677 g/cm3
沸点:
526.7ºC at 760 mmHg
闪点:
73°C
折射率:
1.454
存储条件/存储方法:

 避光,阴凉干燥处,密封保存

稳定性相关:

常温常压下稳定

其它信息:

1.       性状:未确定

2.       密度(g/mL,25/4):未确定

3.       相对蒸汽密度(g/mL,空气=1):未确定

4.       熔点(ºC):未确定

5.       沸点(ºC,常压):未确定

6.       沸点(ºC,5.2kPa):未确定

7.       折射率:未确定

8.       闪点(ºC):未确定

9.       比旋光度(º):未确定

10.    自燃点或引燃温度(ºC):未确定

11.    蒸气压(kPa,25ºC):未确定

12.    饱和蒸气压(kPa,60ºC):未确定

13.    燃烧热(KJ/mol):未确定

14.    临界温度(ºC):未确定

15.    临界压力(KPa):未确定

16.    油水(辛醇/水)分配系数的对数值:未确定

17.    爆炸上限(%,V/V):未确定

18.    爆炸下限(%,V/V):未确定

19.     溶解性:未确定

1,2,3,4-环戊四羧酸二酐 安全信息

海关代码:
2932190090
危险类别码:
R36/37
安全说明:
S25
安全标志:
S25:避免接触眼睛。
危险标志:
Xi

1,2,3,4-环戊四羧酸二酐 毒理性

生态数据:

通常对水是不危害的,若无政府许可,勿将材料排入周围环境.

1,2,3,4-环戊四羧酸二酐 MSDS


Section I.Chemical Product and Company Identification
    Chemical Name 1,2,3,4-Cyclopentanetetracarboxylic Dianhydride
    Portland OR
    Synonym        1H-Cyclopenta[1,2-c:3,4-c']difuran-1,3,4,6(3aH)-tetrone,    
    tetrahydro- (CA INDEX)
    C9H6O6
    Chemical Formula
    CAS Number        6053-68-5    

Section II.        Composition and Information on Ingredients    
    Toxicology Data
    Chemical Name        CAS Number Percent (%)        TLV/PEL    
    Min. 98.0 (T) Not available.        Not available.    
    1,2,3,4-Cyclopentanetetracarboxylic Dianhydride        6053-68-5    

Section III. Hazards Identification
    Acute Health Effects        Irritating to eyes and skin on contact. Inhalation causes irritation of the lungs and respiratory system. Inflammation of the    
    eye is characterized by redness, watering, and itching. Skin inflammation is characterized by itching, scaling, reddening, or,
    occasionally, blistering. Follow safe industrial hygiene practices and always wear proper protective equipment when handling
    this compound.
    Chronic Health Effects        CARCINOGENIC EFFECTS : Not available.    
    MUTAGENIC EFFECTS : Not available.
    TERATOGENIC EFFECTS : Not available.
    DEVELOPMENTAL TOXICITY: Not available.
    Repeated or prolonged exposure to this compound is not known to aggravate existing medical conditions.

Section IV.        First Aid Measures    
    Eye Contact        Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15    
    minutes. Get medical attention.
    Skin Contact        In case of contact, immediately flush skin with plenty of water. Remove contaminated clothing and shoes. Wash clothing    
    before reuse. Thoroughly clean shoes before reuse. Get medical attention.
    If the victim is not breathing, perform mouth-to-mouth resuscitation. Loosen tight clothing such as a collar, tie, belt or
    Inhalation
    waistband. If breathing is difficult, oxygen can be administered. Seek medical attention if respiration problems do not
    improve.
    INDUCE VOMITING by sticking finger in throat. Lower the head so that the vomit will not reenter the mouth and throat.
    Ingestion
    Loosen tight clothing such as a collar, tie, belt or waistband. If the victim is not breathing, perform mouth-to-mouth
    resuscitation. Examine the lips and mouth to ascertain whether the tissues are damaged, a possible indication that the toxic
    material was ingested; the absence of such signs, however, is not conclusive.

Section V.        Fire and Explosion Data    
    Not available.
    May be combustible at high temperature.        Auto-Ignition    
    Flammability
    Flash Points        Flammable Limits        Not available.    
    Not available.
    These products are toxic carbon oxides (CO, CO2).
    Combustion Products
    Fire Hazards        Not available.    
    Risks of explosion of the product in presence of mechanical impact: Not available.
    Explosion Hazards
    Risks of explosion of the product in presence of static discharge: Not available.
    Fire Fighting Media
    SMALL FIRE: Use DRY chemical powder.
    LARGE FIRE: Use water spray, fog or foam. DO NOT use water jet.
    and Instructions
    Consult with local fire authorities before attempting large scale fire-fighting operations.
    Continued on Next Page
    1,2,3,4-Cyclopentanetetracarboxylic Dianhydride

Section VI.        Accidental Release Measures    
    Spill Cleanup        Irritating material.    
    Use a shovel to put the material into a convenient waste disposal container. Finish cleaning the spill by rinsing any
    Instructions
    contaminated surfaces with copious amounts of water. Consult federal, state, and/or local authorities for assistance on
    disposal.

Section VII. Handling and Storage
    IRRITANT. Keep away from heat. Mechanical exhaust required. When not in use, tightly seal the container and store in a
    Handling and Storage
    dry, cool place. Avoid excessive heat and light. Do not breathe dust.
    Information
    Always store away from incompatible compounds such as oxidizing agents, moisture.

Section VIII. Exposure Controls/Personal Protection
    Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below recommended
    Engineering Controls
    exposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to airborne contaminants
    below the exposure limit.
    Splash goggles. Lab coat. Dust respirator. Gloves. Suggested protective clothing might not be sufficient; consult a specialist
    Personal Protection
    BEFORE handling this product. Be sure to use a MSHA/NIOSH approved respirator or equivalent.
    Exposure Limits        Not available.    

Section IX. Physical and Chemical Properties
    Solid. (White crystal~crystalline powder)        Solubility    
    Physical state @ 20°C        Soluble in: Acetone.    
    Not available.
    Specific Gravity
    Molecular Weight        210.14        Partition Coefficient    
    Not available.
    Boiling Point        Not available.        Vapor Pressure        Not applicable.    
    226°C (438.8°F)        Not available.    
    Melting Point        Vapor Density    
    Refractive Index        Not available.        Volatility        Not available.    
    Not available.        Not available.    
    Critical Temperature        Odor    
    Viscosity        Not available.        Taste        Not available.    

Section X.        Stability and Reactivity Data    

This material is stable if stored under proper conditions. (See Section VII for instructions)
    Stability
    Conditions of Instability        Avoid excessive heat and light.    
    Incompatibilities
    Reactive with oxidizing agents, moisture.

Section XI. Toxicological Information
    Not available.
    RTECS Number
    Eye Contact. Ingestion. Inhalation.
    Routes of Exposure
    Not available.
    Toxicity Data
    Chronic Toxic Effects        CARCINOGENIC EFFECTS : Not available.    
    MUTAGENIC EFFECTS : Not available.
    TERATOGENIC EFFECTS : Not available.
    DEVELOPMENTAL TOXICITY: Not available.
    Repeated or prolonged exposure to this compound is not known to aggravate existing medical conditions.
    Irritating to eyes and skin on contact. Inhalation causes irritation of the lungs and respiratory system. Inflammation of the eye
    Acute Toxic Effects
    is characterized by redness, watering, and itching. Skin inflammation is characterized by itching, scaling, reddening, or,
    occasionally, blistering. Follow safe industrial hygiene practices and always wear proper protective equipment when handling
    this compound.

Section XII.        Ecological Information    
    Ecotoxicity        Not available.    
    Environmental Fate        Not available.    
    Continued on Next Page
    1,2,3,4-Cyclopentanetetracarboxylic Dianhydride

Section XIII. Disposal Considerations
    Waste Disposal        Recycle to process, if possible. Consult your local regional authorities. You may be able to dissolve or mix material with a    
    combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber system. Observe all
    federal, state and local regulations when disposing of the substance.

Section XIV. Transport Information
    Not a DOT controlled material (United States).
    DOT Classification
    PIN Number        Not applicable.    
    Proper Shipping Name        Not applicable.    
    Packing Group (PG)        Not applicable.    
    DOT Pictograms

Section XV. Other Regulatory Information and Pictograms
    TSCA Chemical Inventory        This compound is ON the EPA Toxic Substances Control Act (TSCA) inventory list.    
    (EPA)
    WHMIS Classification        On NDSL.    
    (Canada)
    EINECS Number (EEC) 227-964-7
    EEC Risk Statements        R36/37/38- Irritating to eyes, respiratory system and skin.    


SECTION 16 - ADDITIONAL INFORMATION
N/A

1,2,3,4-环戊四羧酸二酐 海关数据

中国海关编码:2932190090

概述:
2932190090 其他结构上有非稠合呋喃环化合物. 增值税率:17.0% 退税率:9.0% 监管条件:无 最惠国关税:6.5% 普通关税:20.0%
申报要素:
品名, 成分含量, 用途
摘要/Summary:
2932190090 other compounds containing an unfused furan ring (whether or not hydrogenated) in the structure VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:20.0%

1,2,3,4-环戊四羧酸二酐 分子结构与计算化学数据

分子结构数据

1   摩尔折射率:41.34

2   摩尔体积(m3/mol):125.3

3   等张比容(90.2K):355.1

4   表面张力(dyne/cm):64.6

5   极化率(10-24cm3):16.38

计算化学数据

1.疏水参数计算参考值(XlogP):-0.9

2.氢键供体数量:0

3.氢键受体数量:6

4.可旋转化学键数量:0

5.互变异构体数量:10

6.拓扑分子极性表面积86.7

7.重原子数量:15

8.表面电荷:0

9.复杂度:373

10.同位素原子数量:0

11.确定原子立构中心数量:0

12.不确定原子立构中心数量:4

13.确定化学键立构中心数量:0

14.不确定化学键立构中心数量:0

15.共价键单元数量:1

1,2,3,4-环戊四羧酸二酐 表征图谱

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