硫酸对硝基苯钾盐一水合物

  • 基本信息
  • 物化性质
  • 安全信息
  • 毒理性
  • MSDS
  • 海关数据
  • 结构与计算化学
  • 上游产品
  • 下游产品
  • 表征图谱

硫酸对硝基苯钾盐一水合物 基本信息

中文名称:
硫酸对硝基苯钾盐一水合物 
中文别名:
4-硝基苯硫酸钾单水合物;
硫酸对硝基苯钾盐一水合物;
4-硝基苯酚磺酸酯钾盐 
英文名称:
Sulfuric acid,mono(4-nitrophenyl) ester, potassium salt (1:1)
英文别名:
P-NITROPHENYL SULFATE POTASSIUM SALT;
p-nitrophenyl potassium sulphate;
potassium 4-nitrophenylsulfate monoester;
p-NITROPHENYL SULFATE;
potassium p-nitrophenylsulfonate;
potassium 4-nitrophenyl sulphate;
potassium p-nitrophenyl sulfate;
POTASSIUM P-NITROPHENYL SULPHATE;
potassium 4-nitrophenyl sulfate;
Sulfuric acid p-nitrophenyl ester;
potassium 4-nitrobenzenesulfonate;
nitrophenyl sulphate;
Sulfuric acid 4-nitrophenyl ester;
4-NITROPHENYL SULFATE;
potassum p-nitrophenyl sulfate;
P-NITROPHENYL SULFATE POTASSIUM 
CAS No.:
6217-68-1
分 子 式:
C6H5NO6S.K
分 子 量:
275.30
精确分子量:
256.94000
PSA:
120.63000
MDL:
MFCD00007466
EINECS:
228-288-5
BRN:
3786392
InChI:
InChI=1/C6H5NO6S/c8-7(9)5-1-3-6(4-2-5)13-14(10,11)12/h1-4H,(H,10,11,12)/p-1
风险术语:
20/21/22-36/37/38
分子结构式:
SDS:
查看

硫酸对硝基苯钾盐一水合物 物化性质

外观与性状:
淡黄色水晶般的固体
熔点:
246-250 °C(lit.)
存储条件/存储方法:

-20℃ 避光,阴凉干燥处,密封保存

稳定性相关:

常温常压下稳定

其它信息:

1.       性状未确定

2.       密度(g/mL,25):未确定

3.       相对蒸汽密度(g/mL,空气=1):未确定

4.       熔点(ºC):246-250

5.       沸点(ºC,常压):未确定

6.       沸点(ºC1.5mmHg):未确定

7.       折射率:未确定

8.       闪点ºC):未确定

9.       比旋光度º):未确定

10.    自燃点或引燃温度(ºC):未确定

11.    蒸气压(20ºC):未确定

12.    饱和蒸气压(kPa,60ºC):未确定

13.    燃烧热(KJ/mol):未确定

14.    临界温度(ºC):未确定

15.    临界压力(KPa):未确定

16.    油水(辛醇/水)分配系数的对数值:未确定

17.    爆炸上限(%,V/V):未确定

18.    爆炸下限(%,V/V):未确定

19.    溶解性:未确定

硫酸对硝基苯钾盐一水合物 安全信息

海关代码:
2920909090
WGK_Germany:
3
德国有关水污染物质的分类清单
危险类别码:
R20/21/22
安全说明:
S26-S36/37/39

硫酸对硝基苯钾盐一水合物 毒理性

毒理学数据:

主要的刺激性影响:

在皮肤上面:刺激皮肤和粘膜

在眼睛上面:刺激的影响

致敏作用:没有已知的敏化现象

生态数据:

对水少是稍微危害的,不要让未稀释或大量的产品接触地下水、水道或污水系统

若无政府许可,勿将材料排入周围环境.

硫酸对硝基苯钾盐一水合物 MSDS

Name: 4-Nitrophenyl Sulfate Potassium Salt Monohydrate 99+% Material Safety Data Sheet
Synonym: P-Nitrophenyl Sulfat
CAS: 6217-68-1
Section 1 - Chemical Product   MSDS Name:4-Nitrophenyl Sulfate Potassium Salt Monohydrate 99+% Material Safety Data Sheet
Synonym:P-Nitrophenyl Sulfat

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
6217-68-1 4-Nitrophenyl Sulfate, Potassium Salt 99+% 228-288-5
Hazard Symbols: None Listed.
Risk Phrases: None Listed.

Section 3 - HAZARDS IDENTIFICATION
  EMERGENCY OVERVIEW
The toxicological properties of this material have not been fully investigated.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation.
Ingestion:
May cause irritation of the digestive tract. The toxicological properties of this substance have not been fully investigated.
Inhalation:
May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated.
Chronic:
No information found.

Section 4 - FIRST AID MEASURES
  Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
  General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Runoff from fire control or dilution water may cause pollution.
Extinguishing Media:
Use agent most appropriate to extinguish fire. Use water spray, dry chemical, carbon dioxide, or appropriate foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
  General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, observing precautions in the Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation.

Section 7 - HANDLING and STORAGE
  Handling:
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation.
Storage:
Keep container closed when not in use. Store in a tightly closed container. Keep refrigerated. (Store below 4C/39F.)

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
  Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 6217-68-1: Personal Protective Equipment Eyes: Wear chemical splash goggles. Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to minimize contact with skin.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
 
Physical State: Crystals
Color: beige yellow
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 246.00 - 250.00 deg C
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C6H4NO6SK.H2O
Molecular Weight: 275.27

Section 10 - STABILITY AND REACTIVITY
  Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, dust generation, excess heat, strong oxidants.
Incompatibilities with Other Materials:
Oxidizing agents.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, irritating and toxic fumes and gases, carbon dioxide, nitrogen, sulfur oxides (SOx), including sulfur oxide and sulfur dioxide.
Hazardous Polymerization: Has not been reported

Section 11 - TOXICOLOGICAL INFORMATION
  RTECS#:
CAS# 6217-68-1 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
4-Nitrophenyl Sulfate, Potassium Salt Monohydrate - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION
 

Section 13 - DISPOSAL CONSIDERATIONS
  Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION
 
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.

Section 15 - REGULATORY INFORMATION
 
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 6217-68-1: No information available.
Canada
CAS# 6217-68-1 is listed on Canada's NDSL List.
CAS# 6217-68-1 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 6217-68-1 is listed on the TSCA inventory.


SECTION 16 - ADDITIONAL INFORMATION
N/A

硫酸对硝基苯钾盐一水合物 海关数据

中国海关编码:2920909090

概述:
2920909090 其他无机酸酯(不包括卤化氢的酯)(包括其盐及它们的卤化,磺化,硝化和亚硝化衍生物)。监管条件:无。增值税率:17.0%。退税率:9.0%。最惠国关税:6.5%。普通关税:30.0%
申报要素:
品名, 成分含量, 用途
摘要/Summary:
2920909090 esters of other inorganic acids of non-metals (excluding esters of hydrogen halides) and their salts; their halogenated, sulphonated, nitrated or nitrosated derivatives。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:6.5%。General tariff:30.0%

硫酸对硝基苯钾盐一水合物 分子结构与计算化学数据

计算化学数据

1、   氢键供体数量:1

2、   氢键受体数量:6

3、   可旋转化学键数量:3

4、   拓扑分子极性表面积(TPSA):107

5、   重原子数量:15

6、   表面电荷:1

7、   复杂度:304

8、   同位素原子数量:0

9、   确定原子立构中心数量: 0

10、   不确定原子立构中心数量:0

11、   确定化学键立构中心数量:0

12、   不确定化学键立构中心数量:0

13、   共价键单元数量:2

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