Sodium cyanoborodeuteride

  • 基本信息
  • 制备方法及用途
  • 物化性质
  • 安全信息
  • 毒理性
  • MSDS
  • 结构与计算化学

Sodium cyanoborodeuteride 基本信息

中文名称:
Sodium cyanoborodeuteride 
中文别名:
氰基硼氘化钠;
氰基硼氘化钠 96 ATOM % D 
英文名称:
Borate(1-), (cyano-kC)trihydro-d3-, sodium (1:1),(T-4)-
英文别名:
sodium,cyano(trideuterio)boranuide;
Sodium cyanoborodeuteride 
CAS No.:
25895-62-9
分 子 式:

CBD3N.Na

分 子 量:
65.86
精确分子量:
66.04450
PSA:
23.79000
MDL:
MFCD00003517
EINECS:
247-318-8
危险品标志:

 

风险术语:

R11R32R33R34R26/27/28

安全术语:

S16S26S45S36/S37/S39

分子结构式:
SDS:
查看

Sodium cyanoborodeuteride 制备方法及用途

制备方法

氘标记化合物制备

用途简介

用途

氘标记化合物制备

Sodium cyanoborodeuteride 物化性质

外观与性状:
白色至淡黄色结晶粉末
熔点:
>242ºC (dec.)(lit.)
存储条件/存储方法:

 

 密闭于阴凉干燥环境中

稳定性相关:

 

遵照规定使用和储存则不会分解。

其它信息:

1.       性状:结晶

Sodium cyanoborodeuteride 安全信息

包装等级:
II
风险类别:
4.3
危险类别码:
R11
安全说明:
16-26-36/37/39-45 25 28A 7 8
危险标志:
F: Flammable;T+: Very toxic;

Sodium cyanoborodeuteride 毒理性

毒理学数据:

有毒,易燃。遇酸能释放有毒气体。

生态数据:

该物质对环境可能有危害,对水体应给予特别注意。

Sodium cyanoborodeuteride MSDS

Name: Sodium cyanoborodeuteride 98 atom % d Material Safety Data Sheet
Synonym:
CAS: 25895-62-9
Section 1 - Chemical Product   MSDS Name:Sodium cyanoborodeuteride 98 atom % d Material Safety Data Sheet
Synonym:

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
25895-62-9 Sodium cyanoborodeuteride, 98 atom % D 98% 247-318-8
Hazard Symbols: T
Risk Phrases: 15 23/24/25 32 45

Section 3 - HAZARDS IDENTIFICATION
  EMERGENCY OVERVIEW
Contact with water liberates extremely flammable gases. Toxic by inhalation, in contact with skin and if swallowed. Contact with acids liberates very toxic gas. May cause cancer.Corrosive.Toxic.Highly flammable.Water-reactive.Hygroscopic (absorbs moisture from the air).
Potential Health Effects
Eye:
Causes eye burns.
Skin:
Causes skin burns. Toxic in contact with skin.
Ingestion:
Poison by ingestion. Causes gastrointestinal tract burns.
Inhalation:
May cause irritation of the respiratory tract with burning pain in the nose and throat, coughing, wheezing, shortness of breath and pulmonary edema. Causes chemical burns to the respiratory tract. May cause abdominal pain, nausea, vomiting, and inflammation of the gums and mouth. Toxic if inhaled.
Chronic:
Not available.

Section 4 - FIRST AID MEASURES
  Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Skin:
Get medical aid. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
  General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Can burn in a fire, releasing toxic vapors.
Extinguishing Media:
Use dry chemical to fight fire.

Section 6 - ACCIDENTAL RELEASE MEASURES
  General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container. Remove all sources of ignition.

Section 7 - HANDLING and STORAGE
  Handling:
Wash thoroughly after handling. Avoid contact with eyes, skin, and clothing. Do not breathe dust, vapor, mist, or gas. Use only in a chemical fume hood.
Storage:
Keep away from heat, sparks, and flame. Store in a cool, dry place.
Store in a tightly closed container. Keep under a nitrogen blanket.
Water free area.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
  Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower.
Exposure Limits CAS# 25895-62-9: Personal Protective Equipment Eyes: Wear chemical splash goggles.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
A NIOSH/MSHA approved air purifying dust or mist respirator or European Standard EN 149.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
 
Physical State: Solid
Color: white to off-white
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: >242 deg C dec
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: CBD3NNa
Molecular Weight: 65.86

Section 10 - STABILITY AND REACTIVITY
  Chemical Stability:
Not available.
Conditions to Avoid:
High temperatures, contact with water.
Incompatibilities with Other Materials:
Oxidizing agents, acids, moist air or water.
Hazardous Decomposition Products:
Hydrogen cyanide, nitrogen oxides, carbon monoxide, carbon dioxide, oxides of boron.
Hazardous Polymerization: Has not been reported.

Section 11 - TOXICOLOGICAL INFORMATION
  RTECS#:
CAS# 25895-62-9 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Sodium cyanoborodeuteride, 98 atom % D - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION
 

Section 13 - DISPOSAL CONSIDERATIONS
  Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION
 
IATA
Shipping Name: WATER-REACTIVE SOLID, TOXIC, N.O.S.*
Hazard Class: 4.3 (6.1)
UN Number: 3134
Packing Group: I
IMO
Shipping Name: WATER-REACTIVE SOLID, TOXIC, N.O.S.
Hazard Class: 4.3 (6.1)
UN Number: 3134
Packing Group: I
RID/ADR
Shipping Name: WATER-REACTIVE SOLID, TOXIC, N.O.S.
Hazard Class: 4.3 (6.1)
UN Number: 3134
Packing group: I

Section 15 - REGULATORY INFORMATION
 
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T
Risk Phrases:
R 45 May cause cancer.
R 15 Contact with water liberates extremely
flammable gases.
R 23/24/25 Toxic by inhalation, in contact with skin
and if swallowed.
R 32 Contact with acids liberates very toxic gas.
Safety Phrases:
S 7/8 Keep container tightly closed and dry.
S 25 Avoid contact with eyes.
S 28A After contact with skin, wash immediately with
plenty of water.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 25895-62-9: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 25895-62-9 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 25895-62-9 is not listed on the TSCA inventory.
It is for research and development use only.


SECTION 16 - ADDITIONAL INFORMATION
N/A

Sodium cyanoborodeuteride 分子结构与计算化学数据

分子结构数据

 

1摩尔折射率:无可用

2、   摩尔体积(cm3/mol):无可用       

3、   等张比容(90.2K):无可用

4、   表面张力(dyne/cm):无可用

5、   极化率:无可用

 

计算化学数据

1.疏水参数计算参考值(XlogP):无

2.氢键供体数量:0

3.氢键受体数量:2

4.可旋转化学键数量:0

5.互变异构体数量:无

6.拓扑分子极性表面积23.8

7.重原子数量:4

8.表面电荷:0

9.复杂度:34.5

10.同位素原子数量:3

11.确定原子立构中心数量:0

12.不确定原子立构中心数量:0

13.确定化学键立构中心数量:0

14.不确定化学键立构中心数量:0

15.共价键单元数量:2

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