(R)-N-Boc-3-(2-呋喃基)丙氨酸; (R)-N-叔丁氧羰基-3-(2-呋喃基)丙氨酸

  • 基本信息
  • 物化性质
  • 安全信息
  • 毒理性
  • MSDS
  • 海关数据
  • 结构与计算化学

(R)-N-Boc-3-(2-呋喃基)丙氨酸; (R)-N-叔丁氧羰基-3-(2-呋喃基)丙氨酸 基本信息

中文名称:
(R)-N-Boc-3-(2-呋喃基)丙氨酸; (R)-N-叔丁氧羰基-3-(2-呋喃基)丙氨酸 
中文别名:
(R)-N-Boc-3-(2-呋喃基)丙氨酸;
BOC-D-2-呋喃基丙氨酸.二环己胺;
(R)-N-BOC-3-(2-呋喃基)丙氨酸;
(R)-N-叔丁氧羰基-3-(2-呋喃基)丙氨酸;
BOC-D-3-(2-呋喃基)-丙氨酸;
BOC-D-3-(2-呋喃基)-丙氨酸.二环己胺;
BOC-3-(2-呋喃基)丙氨酸 
英文名称:
2-Furanpropanoic acid, a-[[(1,1-dimethylethoxy)carbonyl]amino]-,(aR)-
英文别名:
BOC-D-2-FURYLALANINE DCHA SALT;
N-Boc-2-broMo-D-phenylalanine;
FMOC-L-2-BROMO-PHE-OH;
BOC-D-2-BROMOPHENYLALANINE;
Boc-D-2-Br-Phe-OH;
BOC-2-BROMO-D-PHENYLALANINE;
BOC-D-2-BROMOPHE;
N-Boc-D-2-bromophenylalanine;
N-Boc-D-2-furylalanine;
BOC-O-BROMO-D-PHE-OH;
RARECHEM BK PT 0041 
CAS No.:
261380-18-1
分 子 式:

C12H17NO5

分 子 量:
255.27
精确分子量:
255.11100
PSA:
88.77000
MDL:
MFCD01860889
InChI:
InChI=1/C12H17NO5/c1-12(2,3)18-11(16)13-9(10(14)15)7-8-5-4-6-17-8/h4-6,9H,7H2,1-3H3,(H,13,16)(H,14,15)/p-1/t9-/m1/s1
危险品标志:

 

风险术语:

 

安全术语:

 

分子结构式:
SDS:
查看

(R)-N-Boc-3-(2-呋喃基)丙氨酸; (R)-N-叔丁氧羰基-3-(2-呋喃基)丙氨酸 物化性质

密度:
1.207
沸点:
406.4ºC at 760mmHg
闪点:
199.6ºC
蒸汽压:
2.47E-07mmHg at 25°C
存储条件/存储方法:

 

 密闭于阴凉干燥环境中

稳定性相关:

 

  遵照规定使用和储存则不会分解。

其它信息:

1.       性状:白色粉末

2.       密度(g/mL,25/4):无可用

3.       相对蒸汽密度(g/mL,空气=1):无可用

4.       熔点(ºC):132.3

5.       沸点(ºC,常压):无可用

6.       沸点(ºC,5.2kPa):无可用

7.       折射率:无可用

8.       闪点(ºC):无可用

9.       比旋光度(º):无可用

10.    自燃点或引燃温度(ºC):无可用

11.    蒸气压(kPa,25ºC):无可用

12.    饱和蒸气压(kPa,60ºC):无可用

13.    燃烧热(KJ/mol):无可用

14.    临界温度(ºC):无可用

15.    临界压力(KPa):无可用

16.    油水(辛醇/水)分配系数的对数值:无可用

17.    爆炸上限(%,V/V):无可用

18.    爆炸下限(%,V/V):无可用

19.    溶解性:无可用

(R)-N-Boc-3-(2-呋喃基)丙氨酸; (R)-N-叔丁氧羰基-3-(2-呋喃基)丙氨酸 安全信息

海关代码:
2932190090
安全说明:
S24/25
危险标志:
Xi: Irritant;

(R)-N-Boc-3-(2-呋喃基)丙氨酸; (R)-N-叔丁氧羰基-3-(2-呋喃基)丙氨酸 毒理性

生态数据:

 

该物质对环境可能有危害,对水体应给予特别注意。

(R)-N-Boc-3-(2-呋喃基)丙氨酸; (R)-N-叔丁氧羰基-3-(2-呋喃基)丙氨酸 MSDS

Name: (R)-N-BOC-2-Furylalanine 95% (98% E.E.) Material Safety Data Sheet
Synonym: N-tert-Butoxycarbonyl-2-furyl-D-alanin
CAS: 261380-18-1
Section 1 - Chemical Product   MSDS Name:(R)-N-BOC-2-Furylalanine 95% (98% E.E.) Material Safety Data Sheet
Synonym:N-tert-Butoxycarbonyl-2-furyl-D-alanin

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
261380-18-1 (R)-N-BOC-2-Furylalanine 95% unlisted
Hazard Symbols: None Listed.
Risk Phrases: None Listed.

Section 3 - HAZARDS IDENTIFICATION
  EMERGENCY OVERVIEW
Not available.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation. May be harmful if absorbed through the skin.
Ingestion:
May cause irritation of the digestive tract. May be harmful if swallowed.
Inhalation:
May cause respiratory tract irritation. May be harmful if inhaled.
Chronic:
Not available.

Section 4 - FIRST AID MEASURES
  Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Get medical aid. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately.
Notes to Physician:
Treat symptomatically and supportively.

Section 5 - FIRE FIGHTING MEASURES
  General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
  General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container.

Section 7 - HANDLING and STORAGE
  Handling:
Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes.
Storage:
Store in a cool, dry place. Store in a tightly closed container.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
  Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 261380-18-1: Personal Protective Equipment Eyes: Not available.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
 
Physical State: Solid
Color: white to off-white
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C12H17NO5
Molecular Weight: 255.27

Section 10 - STABILITY AND REACTIVITY
  Chemical Stability:
Not available.
Conditions to Avoid:
Incompatible materials.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, carbon dioxide, hydrogen fluoride gas.
Hazardous Polymerization: Has not been reported

Section 11 - TOXICOLOGICAL INFORMATION
  RTECS#:
CAS# 261380-18-1 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
(R)-N-BOC-2-Furylalanine - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION
 

Section 13 - DISPOSAL CONSIDERATIONS
  Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION
 
IATA
No information available.
IMO
No information available.
RID/ADR
No information available.

Section 15 - REGULATORY INFORMATION
 
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 261380-18-1: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 261380-18-1 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 261380-18-1 is not listed on the TSCA inventory.
It is for research and development use only.


SECTION 16 - ADDITIONAL INFORMATION
N/A

(R)-N-Boc-3-(2-呋喃基)丙氨酸; (R)-N-叔丁氧羰基-3-(2-呋喃基)丙氨酸 海关数据

中国海关编码:2932190090

概述:
2932190090 其他结构上有非稠合呋喃环化合物. 增值税率:17.0% 退税率:9.0% 监管条件:无 最惠国关税:6.5% 普通关税:20.0%
申报要素:
品名, 成分含量, 用途
摘要/Summary:
2932190090 other compounds containing an unfused furan ring (whether or not hydrogenated) in the structure VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:20.0%

(R)-N-Boc-3-(2-呋喃基)丙氨酸; (R)-N-叔丁氧羰基-3-(2-呋喃基)丙氨酸 分子结构与计算化学数据

分子结构数据

1摩尔折射率:无可用

2、   摩尔体积(cm3/mol):无可用       

3、   等张比容(90.2K):无可用

4、   表面张力(dyne/cm):无可用

5、   极化率:无可用

计算化学数据

1、   疏水参数计算参考值(XlogP):2.3

2、   氢键供体数量:1

3、   氢键受体数量:5

4、   可旋转化学键数量:5

5、   拓扑分子极性表面积(TPSA):91.6

6、   重原子数量:18

7、   表面电荷:-1

8、   复杂度:305

9、   同位素原子数量:0

10、   确定原子立构中心数量:1

11、   不确定原子立构中心数量:0

12、   确定化学键立构中心数量:0

13、   不确定化学键立构中心数量:0

14、   共价键单元数量:1

推荐供应商更多供应商>>

杭州专肽生物技术有限公司

产品介绍:
产品名称:(R)-N-Boc-3-(2-呋喃基)丙氨酸; (R)-N-叔丁氧羰基-3-(2-呋喃基)丙氨酸 Cas号:261380-18-1 纯度:95% 包装信息:5mg,100mg,10g 价格:洽谈
联系方式:
联系人:向海林 电话:17342063383 手机:

上海楚肽生物科技有限公司

产品介绍:
产品名称:2-Furanpropanoic acid, a-[[(1,1-dimethylethoxy)carbonyl]amino]-,(aR)- Cas号:261380-18-1 纯度:98% 包装信息:1g,10g,100g,1kg 价格:洽谈
联系方式:
联系人:吴经理 电话:021-50673982 手机:17321195801

南京肽业生物科技有限公司

产品介绍:
产品名称:261380-18-1 Cas号:261380-18-1 纯度:98%+ 包装信息:管10mg 价格:洽谈
联系方式:
联系人:徐钊 电话:15952803037 手机:15952803037

浙江奥马药业有限公司

产品介绍:
产品名称:BOC-D-2-呋喃丙氨酸二环己胺盐 Cas号:261380-18-1 纯度:98%-99% 包装信息:2kg 价格:洽谈
联系方式:
联系人:蔡文革 电话:86-576-84058058 手机:

上海迈瑞尔生化科技有限公司

产品介绍:
产品名称:Boc-D-3-(2-呋喃基)丙氨酸 Cas号:261380-18-1 纯度: 包装信息:洽谈 价格:洽谈
联系方式:
联系人:迈瑞尔 电话:021-61259100 手机:

苏州昊赛生物科技有限公司

产品介绍:
产品名称:(R)-N-Boc-3-(2-呋喃基)丙氨酸 Cas号:261380-18-1 纯度: 包装信息:洽谈 价格:洽谈
联系方式:
联系人:朱 电话:0512-67262751 手机:

上海鼎酞实业有限公司

产品介绍:
产品名称:Boc-D-3-(2-呋喃基)-丙氨酸 Cas号:261380-18-1 纯度: 包装信息:洽谈 价格:洽谈
联系方式:
联系人:王小姐 电话:18917339013 手机:

中国浙江省金华市钱江精细化工有限公司

产品介绍:
产品名称:BOC-D-2-呋喃丙氨酸二环己胺盐 Cas号:261380-18-1 纯度:98%-99% 包装信息:2kg 价格:洽谈
联系方式:
联系人: 电话:86-579-82273459 手机:

北京海步国际医药科技发展有限公司

产品介绍:
产品名称:BOC-D-2-呋喃丙氨酸二环己胺盐 Cas号:261380-18-1 纯度:98%-99% 包装信息:2kg 价格:洽谈
联系方式:
联系人: 电话:86-10-67886402 手机: