2-氯-5-硝基肉桂酸

  • 基本信息
  • 物化性质
  • 安全信息
  • 毒理性
  • MSDS
  • 海关数据
  • 结构与计算化学
  • 上游产品
  • 下游产品

2-氯-5-硝基肉桂酸 基本信息

中文名称:
2-氯-5-硝基肉桂酸 
中文别名:
2-氯-5-硝基肉桂酸;
Amiprophos methyl;
Amiprofos-methyl;
Amiprophosmethyl;
BAY ntn6867;
BAY ntn80;
BRN 2000833;
NSC 313446;
NTN 2975;
NTN 6867;
NTN 80;
O-Methyl 2-nitro-4-tolyl isopropylphosphoramidothioate;
O-Methyl O-(4-methyl-2-nitrophenyl) (1-methylethyl)phosphoramidothioate;
Tokunol M;
O-methyl O-(4-methyl-2-nitrophenyl) isopropylthiophosphoramidate;
O-Methyl O-(4-methyl-6-nitrophenyl)-N-isopropylphosphorothioamidate;
Phosphoramidothioic acid, (1 
英文名称:
2-Propenoic acid,3-(2-chloro-5-nitrophenyl)-
英文别名:
2-CHLORO-5-NITROCINNAMIC ACID;
2-chloro-5-nitro-trans-cinnamic acid;
2-Chloro-5-nitrocinnamicacid;
2-Chloro-5-nitrocinnamic acid,predominantly trans;
2-Chlor-5-nitro-trans-zimtsaeure;
2-Chloro-5-nitrocinnaMic Acid;
RARECHEM BK HC T333;
5-Nitro-2-chlorocinnamic acid;
trans-2-Chloro-5-nitrocinnamic acid 
CAS No.:
36015-19-7
分 子 式:
C9H6ClNO4
分 子 量:
227.61
精确分子量:
226.99900
PSA:
83.12000
MDL:
MFCD00063312
BRN:
1972431
InChI:
InChI=1/C9H6ClNO4/c10-8-3-2-7(11(14)15)5-6(8)1-4-9(12)13/h1-5H,(H,12,13)/p-1/b4-1+
风险术语:
36/37/38
分子结构式:
SDS:
查看

2-氯-5-硝基肉桂酸 物化性质

密度:
1.529 g/cm3
熔点:
218-222 °C
沸点:
401.7ºC at 760 mmHg
闪点:
196.7°C
存储条件/存储方法:

密封、阴凉、干燥、通风保存

稳定性相关:

常规情况下不会分解,没有危险反应

其它信息:

1.       性状:粉末

2.       密度(g/mL,20):未确定

3.       相对蒸汽密度(g/mL,空气=1): 未确定

4.       熔点(ºC):219-221

5.       沸点(ºC,常压): 未确定

6.       沸点(ºC,35mm hg):未确定

7.       折射率:未确定

8.       闪点(ºC):未确定

9.       比旋光度(º):未确定

10.    自燃点或引燃温度(ºC): 未确定

11.    蒸气压(kPa,25ºC):未确定

12.    饱和蒸气压(kPa,60ºC): 未确定

13.    燃烧热(KJ/mol):未确定

14.    临界温度(ºC):未确定

15.    临界压力(KPa):未确定

16.    油水(辛醇/水)分配系数的对数值:未确定

17.    爆炸上限(%,V/V):未确定

18.    爆炸下限(%,V/V):未确定

19.    溶解性:未确定

2-氯-5-硝基肉桂酸 安全信息

海关代码:
2916399090
危险类别码:
R36/37/38
安全说明:
S24/25
危险标志:
Xi: Irritant;

2-氯-5-硝基肉桂酸 毒理性

生态数据:

对水是稍微有危害的不要让未稀释或大量的产品接触地下水、水道或者污水系统,若无政府许可,勿将材料排入周围环境

2-氯-5-硝基肉桂酸 MSDS

Name: 2-Chloro-5-Nitrocinnamic Acid 98% Predominantly Trans Material Safety Data Sheet
Synonym: 3-(2-Chloro-5-Nitrophenyl)acrylic Aci
CAS: 36015-19-7
Section 1 - Chemical Product   MSDS Name:2-Chloro-5-Nitrocinnamic Acid 98% Predominantly Trans Material Safety Data Sheet
Synonym:3-(2-Chloro-5-Nitrophenyl)acrylic Aci

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
36015-19-7 2-Chloro-5-Nitrocinnamic Acid 98% unlisted
Hazard Symbols: None Listed.
Risk Phrases: None Listed.

Section 3 - HAZARDS IDENTIFICATION
  EMERGENCY OVERVIEW
The toxicological properties of this material have not been fully investigated.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation.
Ingestion:
May cause irritation of the digestive tract. The toxicological properties of this substance have not been fully investigated.
Inhalation:
May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated.
Chronic:
No information found.

Section 4 - FIRST AID MEASURES
  Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
  General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.
Extinguishing Media:
Use agent most appropriate to extinguish fire. Use water spray, dry chemical, carbon dioxide, or appropriate foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
  General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, observing precautions in the Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation.

Section 7 - HANDLING and STORAGE
  Handling:
Wash thoroughly after handling. Use with adequate ventilation.
Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation.
Storage:
Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
  Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 36015-19-7: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
 
Physical State: Powder
Color: yellow crystalline powder
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 218 - 220 deg C
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C9H6ClNO4
Molecular Weight: 227.61

Section 10 - STABILITY AND REACTIVITY
  Chemical Stability:
Stable at room temperature in closed containers under normal storage and handling conditions.
Conditions to Avoid:
Incompatible materials, dust generation, excess heat.
Incompatibilities with Other Materials:
Strong bases, strong oxidizing agents.
Hazardous Decomposition Products:
Hydrogen chloride, nitrogen oxides, carbon monoxide, irritating and toxic fumes and gases, carbon dioxide.
Hazardous Polymerization: Has not been reported

Section 11 - TOXICOLOGICAL INFORMATION
  RTECS#:
CAS# 36015-19-7 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
2-Chloro-5-Nitrocinnamic Acid - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION
 

Section 13 - DISPOSAL CONSIDERATIONS
  Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION
 
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.

Section 15 - REGULATORY INFORMATION
 
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
S 28A After contact with skin, wash immediately with
plenty of water.
S 37 Wear suitable gloves.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 36015-19-7: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 36015-19-7 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 36015-19-7 is not listed on the TSCA inventory.
It is for research and development use only.


SECTION 16 - ADDITIONAL INFORMATION
N/A

2-氯-5-硝基肉桂酸 海关数据

中国海关编码:2916399090

概述:
2916399090 其他芳香一元羧酸. 增值税率:17.0% 退税率:9.0% 监管条件:无 最惠国关税:6.5% 普通关税:30.0%
申报要素:
品名, 成分含量, 用途, 丙烯酸、丙烯酸盐或酯应报明包装
摘要/Summary:
2916399090 other aromatic monocarboxylic acids, their anhydrides, halides, peroxides, peroxyacids and their derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

2-氯-5-硝基肉桂酸 分子结构与计算化学数据

计算化学数据

1、   疏水参数计算参考值(XlogP):2.6

2、   氢键供体数量:0

3、   氢键受体数量:4

4、   可旋转化学键数量:1

5、   拓扑分子极性表面积(TPSA):83.3

6、   重原子数量:15

7、   表面电荷:-1

8、   复杂度:281

9、   同位素原子数量:0

10、   确定原子立构中心数量:0

11、   不确定原子立构中心数量:0

12、   确定化学键立构中心数量:1

13、   不确定化学键立构中心数量:0

14、   共价键单元数量:1

2-氯-5-硝基肉桂酸 上游产品

2-氯-5-硝基肉桂酸 下游产品

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产品介绍:
产品名称:2-氯-5-硝基肉桂酸 Cas号:36015-19-7 纯度: 包装信息:100kg,200kg,300kg,400kg,500kg 价格:64.0元 - 100.0元
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产品名称:2-氯-5-硝基肉桂酸 Cas号:36015-19-7 纯度:>97.0%(T) 包装信息:25g,25g,25g,25g,25g 价格:4,500.0元 - 4,500.0元
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