亚硫酸钾

  • 基本信息
  • 制备方法及用途
  • 物化性质
  • 安全信息
  • 毒理性
  • MSDS
  • 结构与计算化学

亚硫酸钾 基本信息

中文名称:
亚硫酸钾 
中文别名:
亚硫酸钾;
无水亚硫酸钾;
4,4'-[benzene-1,3-diyldi(E)diazene-2,1-diyl]dibenzene-1,3-diamine;
4,4'-[(4-methylbenzene-1,3-diyl)di(E)diazene-2,1-diyl]bis(5-amino-2-methylanilinium) dichloride;
4,4'-[benzene-1,3-diyldi(E)diazene-2,1-diyl]dibenzene-1,3-diamine dihydrochloride;
4-[(E)-{3-[(Z)-(2,4-diaminophenyl)diazenyl]phenyl}diazenyl]benzene-1,3-diamine dihydrochloride;
Basic Brown1;
Basic Brown 1;
Bismarck brown Y;
Kadmiumchlorid [German];
NSC 51148;
UNII-J6K4F9V3BA;
VI-Cad; 
英文名称:
Sulfurousacid, potassium salt (1:2)
英文别名:
Potassium Sulfite;
POTASSIUM SULFITE;
Potassium sulfite;
Potassium sulfide 
CAS No.:
10117-38-1
分 子 式:
H2O3S.2K
分 子 量:
158.26
精确分子量:
157.88400
PSA:
82.40000
MDL:
MFCD00011387
EINECS:
233-321-1
InChI:
InChI=1/K.H2O3S/c;1-4(2)3/h;(H2,1,2,3)
风险术语:
36/37/38-31
分子结构式:
SDS:
查看

亚硫酸钾 制备方法及用途

制备方法

于碳酸钾水溶液内通入二氧化硫,使其饱和后,加等量的碳酸钠,经蒸发、结晶而得。

合成制备方法

于碳酸钾水溶液内通入二氧化硫,使其饱和后,加等量的碳酸钠,经蒸发、结晶而得。

用途简介

四、用途:分析用

用途

 

亚硫酸钾 物化性质

存储条件/存储方法:

密封阴凉干燥避光保存。

稳定性相关:

白色立方结晶或熔块。在空气中易变色。极易吸湿。性不稳定,撞击或急热能引起爆炸。易溶于水,水溶液呈强碱性。有腐蚀性。

其它信息:

1.      性状:白色无臭粗粉。

2.      密度(g/mL,20℃):1.74

3.      相对蒸汽密度(g/mL,空气=1):未确定

4.      熔点(ºC):912

5.      沸点(ºC,常压):未确定

6.      沸点(ºC,5.2kPa):未确定

7.      折射率:未确定

8.      闪点(ºC):未确定

9.      比旋光度(º):未确定

10.   自燃点或引燃温度(ºC):未确定

11.   蒸气压(kPa,20ºC):未确定

12.   饱和蒸气压(kPa,60ºC):未确定

13.   燃烧热(KJ/mol):未确定

14.   临界温度(ºC):未确定

15.   临界压力(KPa):未确定

16.   油水(辛醇/水)分配系数的对数值:未确定

17.   爆炸上限(%,V/V):未确定

18.   爆炸下限(%,V/V):未确定

19.   溶解性:易溶于水(1g/3.5m1)。难溶于乙醇

亚硫酸钾 安全信息

海关代码:
2832200000
WGK_Germany:
1
德国有关水污染物质的分类清单
危险类别码:
R36/37/38
安全说明:
S26-S36
危险标志:
Xi: Irritant;

亚硫酸钾 毒理性

生态数据:

该物质对环境可能有危害,对水是极其危害的即使小量产品也不能接触地下水,水道或污水系统,未经政府许可勿将材料排入周围环境。

亚硫酸钾 MSDS


Section 1. Chemical Product and Company Identification
    Potassium sulfite
    Common Name/
    Trade Name
    Manufacturer
    Commercial Name(s)
    Synonym
    Chemical Name
    Chemical Family
    Potassium sulfite

Section 4. First Aid Measures
    Eye Contact        Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at    
    least 15 minutes. Cold water may be used. Get medical attention if irritation occurs.
    Skin Contact        Wash with soap and water. Cover the irritated skin with an emollient. Get medical attention if irritation develops.    
    Cold water may be used.
    Serious Skin Contact        Not available.    
    Inhalation        If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get    
    medical attention.
    Serious Inhalation        Not available.    
    Ingestion        Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an    
    unconscious person. If large quantities of this material are swallowed, call a physician immediately. Loosen tight
    clothing such as a collar, tie, belt or waistband.
    Serious Ingestion        Not available.    

Section 5. Fire and Explosion Data
    Flammability of the Product Non-flammable.
    Auto-Ignition Temperature Not applicable.
    Flash Points        Not applicable.    
    Flammable Limits        Not applicable.    
    Not available.
    Products of Combustion
    Fire Hazards in Presence of Not applicable.
    Various Substances
    Explosion Hazards in Presence Risks of explosion of the product in presence of mechanical impact: Not available.
    of Various Substances        Risks of explosion of the product in presence of static discharge: Not available.    
    Fire Fighting Media        Not applicable.    
    and Instructions
    Special Remarks on        Not available.    
    Fire Hazards
    Special Remarks on Explosion Not available.
    Hazards

Section 6. Accidental Release Measures
    Small Spill        Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by    
    spreading water on the contaminated surface and dispose of according to local and regional authority
    requirements.
    Large Spill
    Use a shovel to put the material into a convenient waste disposal container. Finish cleaning by spreading water
    on the contaminated surface and allow to evacuate through the sanitary system.
    Potassium sulfite

Section 7. Handling and Storage
    Precautions        Do not breathe dust. Keep away from incompatibles such as oxidizing agents.    
    Storage        Keep container tightly closed. Keep container in a cool, well-ventilated area. Air Sensitive    

Section 8. Exposure Controls/Personal Protection
    Engineering Controls        Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below    
    recommended exposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to
    airborne contaminants below the exposure limit.
    Personal Protection        Safety glasses. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent. Gloves.    
    Personal Protection in Case of Splash goggles. Full suit. Dust respirator. Boots. Gloves. A self contained breathing apparatus should be used
    a Large Spill        to avoid inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist    
    BEFORE handling this product.
    Exposure Limits        Not available.    

Section 9. Physical and Chemical Properties
    Physical state and appearance        Solid. (Powdered solid.        Crystalline powder. Odor        Odorless.    
    Crystals solid.)
    Taste        Not available.    
    Molecular Weight        158.26 g/mole    
    White.
    Color
    pH (1% soln/water)        Not available.    
    Boiling Point        Not available.    
    Melting Point        Not available.    
    Critical Temperature        Not available.    
    Not available.
    Specific Gravity
    Vapor Pressure        Not applicable.    
    Not available.
    Vapor Density
    Volatility        Not available.    
    Odor Threshold        Not available.    
    Not available.
    Water/Oil Dist. Coeff.
    Ionicity (in Water)        Not available.    
    See solubility in water.
    Dispersion Properties
    Solubility        Soluble in cold water.    

Section 10. Stability and Reactivity Data
    Stability        The product is stable.    
    Not available.
    Instability Temperature
    Conditions of Instability        Incompatible materials, air    
    Incompatibility with various        Reactive with oxidizing agents.    
    substances        Slightly reactive to reactive with acids.    
    Corrosivity        Non-corrosive in presence of glass.    
    Potassium sulfite
    Air sensitive. Oxidizes in air to sulfate.
    Special Remarks on
    Reactivity
    Special Remarks on        Not available.    
    Corrosivity
    Polymerization        Will not occur.    

Section 11. Toxicological Information
    Routes of Entry        Eye contact. Inhalation. Ingestion.    
    Toxicity to Animals        LD50: Not available.    
    LC50: Not available.
    Chronic Effects on Humans Not available.
    Other Toxic Effects on
    Slightly hazardous in case of skin contact (irritant, sensitizer), of ingestion, of inhalation.
    Humans
    Special Remarks on        Not available.    
    Toxicity to Animals
    Special Remarks on        Not available.    
    Chronic Effects on Humans
    Special Remarks on other        Potential Health Effects:    
    Toxic Effects on Humans        Skin: May cause skin irritation. May cause contact dermatitis.    
    Eyes: May cause eye irritation. May cause conjunctivitis in sensitive individuals.
    Inhalation: Can cause respiratory tract irritation. Inhalation can also trigger the onset of hypersensivity reactions,
    nasal pruritus(itiching) and rhinorrhea (runny nose in sensitized individuals.
    Ingestion: When ingested it can cause gastric irritation by liberation of sulfurous acid. Because of rapid oxidation
    to sulfate, sulfites are well tolerated until large doses are reached. Ingestion of large doses can cause nausea,
    vomiting, abdominal pain, violet colic and diarrhea. It may also cause circulatory disturbances, hypotension (low
    blood pressure), and may affect behavior/central nervous system (central nervous system stimulation followed by
    depression, seizures). In animals, hypotension, cyanosis, and cardiovascular collapse have been described
    following ingestion of lethal doses of sulfites. Some asthmatics are said to be dangerously sensitive to minute
    amounts of sulfites in foods. Symptoms of hypersensitivity are bronchoconstriction, swelling of the tongue,
    diffuculty swallowing, diaphoresis (sweating), flushing, urticaria (hives), tachycardia (rapid heart beat),
    hypotension, and anaphylaxis.

Section 12. Ecological Information
    Ecotoxicity        Not available.    
    BOD5 and COD        Not available.    
    Products of Biodegradation        Possibly hazardous short term degradation products are not likely. However, long term degradation products may    
    arise.
    Toxicity of the Products        The product itself and its products of degradation are not toxic.    
    of Biodegradation
    Special Remarks on the        Not available.    
    Products of Biodegradation

Section 13. Disposal Considerations
    Waste Disposal        Waste must be disposed of in accordance with federal, state and local environmental    
    control regulations.
    Potassium sulfite

Section 14. Transport Information
    DOT Classification        Not a DOT controlled material (United States).    
    Identification        Not applicable.    
    Not applicable.
    Special Provisions for
    Transport
    DOT (Pictograms)

Section 15. Other Regulatory Information and Pictograms
    TSCA 8(b) inventory: Potassium sulfite
    Federal and State
    Regulations
    California        California prop. 65: This product contains the following ingredients for which the State of California has found    
    to cause cancer which would require a warning under the statute: No products were found.
    Proposition 65
    Warnings
    California prop. 65: This product contains the following ingredients for which the State of California has found
    to cause birth defects which would require a warning under the statute: No products were found.
    Other Regulations        EINECS: This product is on the European Inventory of Existing Commercial Chemical Substances (EINECS No.    
    233-321-1).
    Canada: Listed on Canadian Domestic Substance List (DSL).
    China: Listed on National Inventory.
    Japan: Listed on National Inventory (ENCS).
    Korea: Listed on National Inventory (KECI).
    Philippines: Listed on National Inventory (PICCS).
    Australia: Listed on AICS.
    WHMIS (Canada) Not controlled under WHMIS (Canada).
    Other Classifications
    DSCL (EEC)
    This product is not classified according Not applicable.
    to the EU regulations.
    Health Hazard
    HMIS (U.S.A.)        1 National Fire Protection    
    0 Flammability
    0 Association (U.S.A.)
    Fire Hazard
    1 0 Reactivity
    Health
    Reactivity
    0
    Specific hazard
    Personal Protection
    E
    WHMIS (Canada)
    (Pictograms)
    DSCL (Europe)
    (Pictograms)
    TDG (Canada)
    (Pictograms)
    Potassium sulfite
    ADR (Europe)
    (Pictograms)
    Protective Equipment
    Gloves.
    Lab coat.
    Dust respirator. Be sure to use an
    approved/certified respirator or
    equivalent.


SECTION 16 - ADDITIONAL INFORMATION
N/A

亚硫酸钾 分子结构与计算化学数据

分子结构数据

1、摩尔折射率:无可用的

2、摩尔体积(cm3/mol):无可用的

3、等张比容(90.2K):无可用的

4、表面张力(dyne/cm):无可用的

5、介电常数:无可用的

6、极化率(10-24cm3):无可用的

7、单一同位素质量:157.884228 Da

8、标称质量:158 Da

9、平均质量:158.2598 Da

计算化学数据

1.疏水参数计算参考值(XlogP):无

2.氢键供体数量:0

3.氢键受体数量:4

4.可旋转化学键数量:0

5.互变异构体数量:无

6.拓扑分子极性表面积82.4

7.重原子数量:6

8.表面电荷:0

9.复杂度:18.8

10.同位素原子数量:0

11.确定原子立构中心数量:0

12.不确定原子立构中心数量:0

13.确定化学键立构中心数量:0

14.不确定化学键立构中心数量:0

15.共价键单元数量:3

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