磷酸铵

  • 基本信息
  • 制备方法及用途
  • 物化性质
  • MSDS
  • 结构与计算化学

磷酸铵 基本信息

中文名称:
磷酸铵 
中文别名:
磷酸二氢铵 
英文名称:
Phosphoric acid,ammonium salt (1:?)
英文别名:
azane,phosphoric acid;
phosphoric acid amine;
FR-CROS 282;
Amfos;
Taikarin FN;
Ammonium orthophosphate;
Taikarin F;
Phosphoric acid,ammonium salt 
CAS No.:
10124-31-9
分 子 式:
H3N.xH3O4P
分 子 量:
149.09
精确分子量:
149.05700
PSA:
97.29000
EINECS:
233-330-0
分子结构式:
SDS:
查看

磷酸铵 制备方法及用途

制备方法

中和法将磷酸氢二铵加入化料罐,溶解于60℃左右的热水中,配制成浓度约50%的溶液,经过滤后把清液送入反应器中,在搅拌下缓慢加入27%~28%氨水进行中和反应,至PH值为14时生成磷酸三铵溶液,把反应液放入冷却结晶器中,待全部析出磷酸三铵结晶后经离心分离、干燥,制得磷酸三铵。

合成制备方法

中和法将磷酸氢二铵加入化料罐,溶解于60℃左右的热水中,配制成浓度约50%的溶液,经过滤后把清液送入反应器中,在搅拌下缓慢加入27%~28%氨水进行中和反应,至PH值为14时生成磷酸三铵溶液,把反应液放入冷却结晶器中,待全部析出磷酸三铵结晶后经离心分离、干燥,制得磷酸三铵。

用途简介

是一种高浓度氮磷复合肥料,可用作甘蔗生长的催芽剂。也用作木材防火剂,水处理的软水剂,生物培养剂,分析化学试剂。

用途

是一种高浓度氮磷复合肥料,可用作甘蔗生长的催芽剂。也用作木材防火剂,水处理的软水剂,生物培养剂,分析化学试剂。

磷酸铵 物化性质

外观与性状:
白色固体
熔点:
155ºC with decomp
沸点:
158ºC at 760 mmHg
蒸汽压:
1.41mmHg at 25°C
稳定性相关:

性质不稳定,水溶液加热则失去两个分子氨而成磷酸二氢铵。露置空气中能失去部分氨。

其它信息:

1.性状:无色透明的片晶或白色菱形结晶。

2溶解性:易溶于水,水溶液呈中性或弱碱性;微溶于稀氨水;不溶于液氨、丙酮、乙醇和乙醚。。

磷酸铵 MSDS

Name: Triammonium orthophosphate trihydrate Material Safety Data Sheet
Synonym: Phosphoric acid, ammonium salt, trihydrate
CAS: 10124-31-9
Section 1 - Chemical Product   MSDS Name:Triammonium orthophosphate trihydrate Material Safety Data Sheet
Synonym:Phosphoric acid, ammonium salt, trihydrate

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
10124-31-9 Phosphoric acid, ammonium salt (anhydr >95 233-330-0
Hazard Symbols: None Listed.
Risk Phrases: None Listed.

Section 3 - HAZARDS IDENTIFICATION
  EMERGENCY OVERVIEW
Not available.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation.
Ingestion:
Ingestion of large amounts may cause gastrointestinal irritation.
Inhalation:
Causes respiratory tract irritation. Inhalation of high concentrations of ammonia vapors may cause shortness of breath, bronchospasm, chest pain and pulmonary edema which may be fatal.
Chronic:
No information found.

Section 4 - FIRST AID MEASURES
  Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid if irritation develops or persists. Flush skin with plenty of soap and water.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical aid if irritation or symptoms occur.
Inhalation:
Remove from exposure and move to fresh air immediately. Get medical aid if cough or other symptoms appear.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
  General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.
Extinguishing Media:
Substance is nonflammable; use agent most appropriate to extinguish surrounding fire.

Section 6 - ACCIDENTAL RELEASE MEASURES
  General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, observing precautions in the Protective Equipment section.

Section 7 - HANDLING and STORAGE
  Handling:
Wash thoroughly after handling. Wash hands before eating. Use with adequate ventilation. Avoid contact with skin and eyes. Avoid ingestion and inhalation.
Storage:
Store in a cool, dry place. Keep container closed when not in use.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
  Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 10124-31-9: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
 
Physical State: Solid
Color: white
Odor: Not available.
pH: alkaline
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: Not available.
Solubility in water: Soluble.
Specific Gravity/Density: Not available.
Molecular Formula: (NH4)3PO4.3H2O
Molecular Weight: 203.1157

Section 10 - STABILITY AND REACTIVITY
  Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Dust generation.
Incompatibilities with Other Materials:
Strong acids.
Hazardous Decomposition Products:
Oxides of phosphorus, nitrogen oxides (NOx) and ammonia (NH3).
Hazardous Polymerization: Has not been reported

Section 11 - TOXICOLOGICAL INFORMATION
  RTECS#:
CAS# 10124-31-9 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Phosphoric acid, ammonium salt (anhydrous) - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION
 

Section 13 - DISPOSAL CONSIDERATIONS
  Products which are considered hazardous for supply are classified as Special Waste and the disposal of such chemicals is covered by regulations which may vary according to location. Contact a specialist disposal company or the local waste regulator for advice. Empty containers must be decontaminated before returning for recycling.

Section 14 - TRANSPORT INFORMATION
 
IATA
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing Group:
IMO
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing Group:
RID/ADR
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing group:

Section 15 - REGULATORY INFORMATION
 
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
WGK (Water Danger/Protection)
CAS# 10124-31-9: 1
Canada
CAS# 10124-31-9 is listed on Canada's DSL List.
CAS# 10124-31-9 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 10124-31-9 is listed on the TSCA inventory.


SECTION 16 - ADDITIONAL INFORMATION
N/A

磷酸铵 分子结构与计算化学数据

计算化学数据

1.疏水参数计算参考值(XlogP):无

2.氢键供体数量:4

3.氢键受体数量:5

4.可旋转化学键数量:0

5.互变异构体数量:无

6.拓扑分子极性表面积78.8

7.重原子数量:6

8.表面电荷:0

9.复杂度:49.8

10.同位素原子数量:0

11.确定原子立构中心数量:0

12.不确定原子立构中心数量:0

13.确定化学键立构中心数量:0

14.不确定化学键立构中心数量:0

15.共价键单元数量:2

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