高氯酸钙

  • 基本信息
  • 制备方法及用途
  • 物化性质
  • 安全信息
  • MSDS
  • 结构与计算化学

高氯酸钙 基本信息

中文名称:
高氯酸钙 
中文别名:
六水高氯酸镉;
高氯酸钙 
英文名称:
Perchloric acid,cadmium salt, hexahydrate (8CI,9CI)
英文别名:
CADMIUM PERCHLORATE HEXAHYDRATE;
CADMIUM PERCHLORATE,HEXAHYDRATE REAGENT;
CADMIUM PERCHLORATE,99.9 (METALS BASIS);
Cadmium perchlorate hexahydrate,99.9 (metals basis);
Cadmiumperchloratehexahydrate;
Cadmium Perchlorate Hexahydrate;
CADMIUM PERCHLORATE 6-HYDRATE 
CAS No.:
10326-28-0
分 子 式:
Cd.2ClHO4.6H2O
分 子 量:
419.39
精确分子量:
419.86400
PSA:
203.92000
MDL:
MFCD00015992
风险术语:
R8;R20/21/22;R50/53
安全术语:
S60;S61
分子结构式:
SDS:
查看

高氯酸钙 制备方法及用途

制备方法

将碳酸镉与高氯酸水溶液反应、蒸发浓缩得到晶体。

合成制备方法

将碳酸镉与高氯酸水溶液反应、蒸发浓缩得到晶体。

用途简介

高氯酸钙 物化性质

稳定性相关:

65~70℃分解为四水合物。

其它信息:

1.       性状:白色晶体

2.       密度(g/mL,25/4℃):2.37

3.       相对蒸汽密度(g/mL,空气=1):不确定

4.       熔点(ºC):129.4

5.       沸点(ºC,0.67kpa或5 mmHg):不确定

6.       折射率:不确定

7.       闪点(ºC):不确定

8.       比旋光度(ºC):不确定

9.       自燃点或引燃温度(ºC)不确定

10.    蒸气压(kPa,25ºC):不确定

11.    饱和蒸气压(kPa,60ºC):不确定

12.    燃烧热(KJ/mol):不确定

13.    临界温度(ºC):50.3

14.    临界压力(KPa):不确定

15.    油水(辛醇/水)分配系数的对数值:不确定

16.    爆炸上限(%,V/V):不确定

17.    爆炸下限(%,V/V):不确定

18.    溶解性:溶于水。

高氯酸钙 安全信息

包装等级:
II
风险类别:
5.1
危险类别码:
8-36/37/38
安全说明:
17-26-36/37/39
安全标志:
S60:本物质残余物和容器必须作为危险废物处理。
S61:避免排放到环境中。参考专门的说明/安全数据表。

高氯酸钙 MSDS


Section 1: Product Identification
   Chemical Name:       Cadmium perchlorate hexahydrate, 99%    
   CAS Registry Number:       10326-28-0    
   Formula:       Cd(ClO4)2.6H2O    
   EINECS Number:       none    
   Chemical Family:       metal perchlorate salt    
   Synonym:       Perchloric acid, Cadmium(II) salt, hexahydrate    

Section 2: Composition and Information on Ingredients
   Ingredient       CAS Number       Percent       ACGIH (TWA)       OSHA (PEL)    
   Title Compound       10326-28-0       100%       0.002mg/m3       0.005mg/m3    

Section 3: Hazards Identification
   Oral toxicity and inhalation toxicity is high. Damage to liver and kidney function may result. May cause cancer.
   Emergency Overview:
   Primary Routes of Exposure:       Ingestion    
   Eye Contact:       May cause slight to mild irritation of the eyes.    
   Skin Contact:       May cause slight to mild irritation of the skin.    
   Inhalation of dust and fumes can lead a cough, headache, shortness of breath, chest pains, and pulmonary
   Inhalation:
   edema.
   Ingestion:       Ingestion may lead to sudden nausea, vomiting, bloody diarrhea, weakness, and convulsions.    
   Acute Health Affects:       Toxic by inhalation and if swallowed. May be irritating.    
   Loss of sense of smell, weight loss, liver and kidney damage. Cadmium is a recognized carcinogen of the
   Chronic Health Affects:       connective tissue, lungs and the liver. Perchlorates reversibly inhibit thyroid iodine uptake. Kidney function    
   may be affected.
   NTP:       Yes    
   IARC:       Yes    
   OSHA:       No    

SECTION 4: First Aid Measures
   Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
   Eye Exposure:
   assistance in keeping their eye lids open. Get immediate medical attention.
   Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
   Skin Exposure:
   irritation persists.
   Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
   Inhalation:
   in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
   Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
   Ingestion:
   vomiting only if directed by medical personnel.

SECTION 5: Fire Fighting Measures
   Flash Point:       no data    
   Autoignition Temperature:       no data    
   Explosion Limits:       no data    
   Extinguishing Medium:       Water spray    
   Spray closed containers with water until fire is out. Avoid contact with combustible material. Fire fighters
   Special Fire Fighting Procedures:
   should be equipped with a NIOSH approved self-contained breathing apparatus.
   Hazardous Combustion and       If involved in a fire this material may emit corrosive hydrogen chloride fumes.    
   Decomposion Products:
   Releases oxygen on heating. May decompose explosively under fire fighting conditions. Do not mix with
   Unusual Fire or Explosion Hazards:
   combustibles.

SECTION 6: Accidental Release Measures
   Do not mix spilled powder with any combustible materials, such as sawdust. Sweep up the solid and dilute
   Spill and Leak Procedures:
   with water.

SECTION 7: Handling and Storage
   Handling and Storage:       Store in a tightly sealed container in a cool dry place away from combustible and flammable materials.    

SECTION 8: Exposure Controls and Personal Protection
   Eye Protection:       Always wear approved safety glasses when handling a chemical substance in the laboratory.    
   Skin Protection:       Wear protective clothing and gloves.    
   Ventilation:       If possible, handle the material in an efficient fume hood.    
   If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator
   Respirator:
   Protection Program to be in compliance with 29 CFR 1910.134.
   Ventilation:       If possible, handle the material in an efficient fume hood.    
   Additional Protection:       No additional protection required.    

SECTION 9: Physical and Chemical Properties
   Color and Form:       white xtl.    
   Molecular Weight:       311.30 (419.39)    
   Melting Point:       no data    
   Boiling Point:       no data    
   Vapor Pressure:       no data    
   Specific Gravity:       no data    
   Odor:       none    
   Solubility in Water:       very soluble    

SECTION 10: Stability and Reactivity
   Stability:       Air and moisture stable solid    
   Hazardous Polymerization:       no hazardous polymerization    
   Conditions to Avoid:       Any contact with combustible matter.    
   Incompatibility:       Reducing agents, organic matter, active metals, phosphorus, sulfur, hydrazine, hydroxylamine, strong acids    
   Decomposition Products:       Oxygen, Cadmium oxide, hydrogen chloride,    

SECTION 11: Toxicological Information
   RTECS Data:       No specific information available on this product.    
   Carcinogenic Effects:       Carcinogen (as Ca)    
   Mutagenic Effects:       No data available    
   Tetratogenic Effects:       No data available    

SECTION 12: Ecological Information
   Ecological Information:       No data available    

SECTION 13: Disposal Considerations
   Disposal:       Dispose of according to local, state and federal regulations.    

SECTION 14: Transportation
   Shipping Name (CFR):       Oxidizing solid, Toxic, N.O.S.    
   Hazard Class (CFR):       5.1    
   Additional Hazard Class (CFR):       6.1    
   Packaging Group (CFR):       II    
   UN ID Number (CFR):       UN# 3087    
   Shipping Name (IATA):       Oxidizing Solid, Toxic, N.O.S.    
   Hazard Class (IATA):       5.1    
   Additional Hazard Class (IATA):       6.1    
   Packaging Group (IATA):       II    
   UN ID Number (IATA):       UN# 3087    

SECTION 15: Regulatory Information
   TSCA:       Not listed in the TSCA inventory.    
   SARA (Title 313):       Title compound: See Category Code N078 for reporting.    
   Second Ingredient:       none    


SECTION 16 - ADDITIONAL INFORMATION
N/A

高氯酸钙 分子结构与计算化学数据

分子结构数据

1、摩尔折射率:无可用的

2、摩尔体积(cm3/mol):无可用的

3、等张比容(90.2K):无可用的

4、表面张力(dyne/cm):无可用的

5、介电常数:无可用的

6、极化率(10-24cm3):无可用的

7、单一同位素质量:419.863769 Da

8、标称质量:420 Da

9、平均质量:419.4039 Da

计算化学数据

1.疏水参数计算参考值(XlogP):无

2.氢键供体数量:0

3.氢键受体数量:8

4.可旋转化学键数量:0

5.互变异构体数量:无

6.拓扑分子极性表面积149

7.重原子数量:11

8.表面电荷:0

9.复杂度:95.8

10.同位素原子数量:0

11.确定原子立构中心数量:0

12.不确定原子立构中心数量:0

13.确定化学键立构中心数量:0

14.不确定化学键立构中心数量:0

15.共价键单元数量:3

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