Section 1: Product Identification
Chemical Name: Iron (III) fluoride trihydrate, 98%
CAS Registry Number: 15469-38-2
Formula: FeF3.3H2O
EINECS Number: 232-002-4
Chemical Family: metal halide
Synonym: Ferric fluoride hydrate
Section 2: Composition and Information on Ingredients
Ingredient CAS Number Percent ACGIH (TWA) OSHA (PEL)
Title Compound 15469-38-2 100% 1mg/m3 (as Fe ) no data
Section 3: Hazards Identification
Material hydrolyzes in contact with moisture releasing toxic and corrosive hydrofluoric acid. Causes delayed,
Emergency Overview:
deep, slow healing, painful burns. Soluble iron is a poison by ingestion.
Primary Routes of Exposure: Ingestion, inhalation, skin, eyes
Eye Contact: Causes serious eye damage. Effects may not immediately appear.
Skin Contact: Prolonged contact with skin causes delayed deep slow healing painful burns.
Inhalation: Dust or hydrofluoric acid fumes will cause chemical burns to the respiratory tract.
May cause vomiting, and painful abdominal burns. Soluble iron salts may cause poisoning, liver damage and
Ingestion:
coma.
Fluoride poisoning may cause , weakness, coma, and respiratory paralysis, eye and skin burns and pulmonary
Acute Health Affects:
edema. iron poisoning causes pink urine, liver damage, coma and death.
Prolonged exposure to soluble fluorine compounds can cause deterioration of bone and tooth structure, and
Chronic Health Affects:
kidney damage. Iron may damage the liver and pancreas and cause pulmonary fibrosis.
NTP: No
IARC: No
OSHA: No
SECTION 4: First Aid Measures
Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
Eye Exposure:
assistance in keeping their eye lids open. Get immediate medical attention.
Wash the affected area with water. Remove contaminated clothes if necessary. Apply calcium gluconate jelly
Skin Exposure:
or water soluble calcium salts as antidote. Seek medical assistance.
Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
Inhalation:
in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
Ingestion:
vomiting only if directed by medical personnel.
SECTION 5: Fire Fighting Measures
Flash Point: not applicable
Autoignition Temperature: none
Explosion Limits: none
Extinguishing Medium: none required
If involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure self-contained
Special Fire Fighting Procedures:
breathing apparatus and full protective clothing.
Hazardous Combustion and If involved in a fire this material may emit corrosive hydrogen fluoride fumes.
Decomposion Products:
Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards.
SECTION 6: Accidental Release Measures
To avoid raising dust, small spills can be mixed with powdered sodium bicarbonate, lime, or calcium carbonate
Spill and Leak Procedures:
and swept up.
SECTION 7: Handling and Storage
Store material in a tightly sealed bottle away from moisture. If possible, handle material in an efficient fume
Handling and Storage:
hood. Prolonged exposure to the atmosphere may lead to degradation of the product.
SECTION 8: Exposure Controls and Personal Protection
Eye Protection: Always wear approved safety glasses when handling a chemical substance in the laboratory.
Skin Protection: Wear protective clothing and gloves. Consult with glove manufacturer to determine the proper type of glove.
Ventilation: If possible, handle the material in an efficient fume hood.
If in form of fine dust and ventilation is not available a respirator should be worn. The use of respirators
Respirator:
requires a Respirator Protection Program to be in compliance with 29 CFR 1910.134.
Ventilation: If possible, handle the material in an efficient fume hood.
Additional Protection: No additional protection required.
SECTION 9: Physical and Chemical Properties
Color and Form: light yellow pwdr.
Molecular Weight: 112.84 (166.89)
Melting Point: no data
Boiling Point: no data
Vapor Pressure: no data
Specific Gravity: no data
Odor: none
Solubility in Water: slightly soluble
SECTION 10: Stability and Reactivity
Stability: air and moisture stable
Hazardous Polymerization: no hazardous polymerization
Conditions to Avoid: contact with moisture
Incompatibility: Mineral acids and active metals
Decomposition Products: with moisture: hydrofluoric acid
SECTION 11: Toxicological Information
RTECS Data: No information available in the RTECS files.
Carcinogenic Effects: no data
Mutagenic Effects: no data
Tetratogenic Effects: no data
SECTION 12: Ecological Information
Ecological Information: No information available
SECTION 13: Disposal Considerations
Disposal: Dispose of according to local, state and federal regulations.
SECTION 14: Transportation
Shipping Name (CFR): Corrosive solids, N.O.S.
Hazard Class (CFR): 8
Additional Hazard Class (CFR): NA
Packaging Group (CFR): III
UN ID Number (CFR): UN# 1759
Shipping Name (IATA): Corrosive solid, N.O.S.
Hazard Class (IATA): 8
Additional Hazard Class (IATA): NA
Packaging Group (IATA): III
UN ID Number (IATA): UN# 1759
SECTION 15: Regulatory Information
TSCA: Not listed in the TSCA inventory.
SARA (Title 313): Title compound not reportable under SARA 313.
Second Ingredient: none
SECTION 16 - ADDITIONAL INFORMATION
N/A
C
