三(四甲基环戊二烯基)铵(III)

  • 基本信息
  • 制备方法及用途
  • 物化性质
  • 安全信息
  • 毒理性
  • MSDS
  • 结构与计算化学

三(四甲基环戊二烯基)铵(III) 基本信息

中文名称:
三(四甲基环戊二烯基)铵(III) 
中文别名:
硫酸钕;
三(四甲基环戊二烯基)铵(III) 
英文名称:
Neodymium,tris[(1,2,3,4,5-h)-1,2,3,4-tetramethyl-2,4-cyclopentadien-1-yl]-
英文别名:
neodymium(3+),1,2,3,5-tetramethylcyclopenta-1,3-diene;
TRIS(TETRAMETHYLCYCLOPENTADIENYL)NEODYMIUM;
Tris(tetramethylcyclopentadienyl)neodymium (99.9% Nd) (REO);
TRIS(TETRAMETHYLCYCLOPENTADIENYL)NEODYMIUM, 99% (99.9%-ND) (REO);
99.9%-Nd)(REO);
tris(tetramethylcyclopentadienyl)neodymium(iii);
Tris(tetramethylcyclopentadienyl)neodymium(III), 99% (99.9%-Nd) (REO) 
CAS No.:
164528-22-7
分 子 式:
C27H39Nd
分 子 量:
507.85
精确分子量:
505.21300
PSA:
0.00000
InChI:
The Key: CUUNQYWJDSFHKJ-UHFFFAOYSA-N
危险品标志:
FlammableF
风险术语:
R11;R18
安全术语:
S16
分子结构式:
SDS:
查看

三(四甲基环戊二烯基)铵(III) 制备方法及用途

制备方法

科研试剂,生化研究

用途简介

三(四甲基环戊二烯基)铵(III) 物化性质

闪点:
120 °F
存储条件/存储方法:

保存方法:密闭,阴凉,通风干燥处

稳定性相关:

避氧化物、水分、空气

其它信息:

1.      性状:固体

三(四甲基环戊二烯基)铵(III) 安全信息

包装等级:
II
风险类别:
4.1
危险类别码:
R11
安全说明:
16
安全标志:
S16:远离火源。
危险标志:
F: Flammable;

三(四甲基环戊二烯基)铵(III) 毒理性

生态数据:

1、其它有害作用:通常对水是稍微危害的,若无政府许可,勿将材料排入周围环境。

三(四甲基环戊二烯基)铵(III) MSDS


Section 1: Product Identification
   Chemical Name:       Tris(tetramethylcyclopentadienyl)neodymium (99.9%-Nd) (REO)    
   CAS Registry Number:       164528-22-7    
   Formula:       [(CH3)4C5H]3Nd    
   EINECS Number:       none    
   Chemical Family:       organometallic complexes    
   Synonym:       None    

Section 2: Composition and Information on Ingredients
   Ingredient       CAS Number       Percent       ACGIH (TWA)       OSHA (PEL)    
   Title compound       164528-22-7       100%       no data       no data    

Section 3: Hazards Identification
   Emergency Overview:       Irritating to the respiratory tract, skin and eyes. May be harmful if swallowed.    
   Primary Routes of Exposure:       Ingestion, eyes    
   Eye Contact:       Causes slight to mild irritation of the eyes.    
   Skin Contact:       Causes slight to mild irritation of the skin.    
   Inhalation:       Irritating to skin, eyes and respiratory tract.    
   Ingestion:       Ingestion may lead to vomiting, and diarrhea.    
   Acute Health Affects:       Irritating to skin, eyes and respiratory tract.    
   Chronic Health Affects:       No information available on long-term chronic effects.    
   NTP:       No    
   IARC:       No    
   OSHA:       No    

SECTION 4: First Aid Measures
   Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
   Eye Exposure:
   assistance in keeping their eye lids open. Get immediate medical attention.
   Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
   Skin Exposure:
   irritation persists.
   Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
   Inhalation:
   in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
   Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
   Ingestion:
   vomiting only if directed by medical personnel.

SECTION 5: Fire Fighting Measures
   Flash Point:       none    
   Autoignition Temperature:       none    
   Explosion Limits:       none    
   Extinguishing Medium:       carbon dioxide, foam or dry powder    
   If this product is involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure
   Special Fire Fighting Procedures:
   self- contained breathing apparatus and full protective clothing.
   Hazardous Combustion and       If involved in a fire this material may emit irritating fumes.    
   Decomposion Products:
   Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards.

SECTION 6: Accidental Release Measures
   Spill and Leak Procedures:       Small spills can be mixed with vermiculite or sodium carbonate and swept up.    

SECTION 7: Handling and Storage
   Keep material in a tightly sealed container. Prolonged exposure to the air will result in degradation of the
   Handling and Storage:
   product. Handle and store material under an inert atmosphere of nitrogen or argon.

SECTION 8: Exposure Controls and Personal Protection
   Eye Protection:       Always wear approved safety glasses when handling a chemical substance in the laboratory.    
   Skin Protection:       Wear protective clothing and gloves.    
   Ventilation:       If possible, handle the material in an efficient fume hood.    
   If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator
   Respirator:
   Protection Program to be in compliance with 29 CFR 1910.134.
   Ventilation:       If possible, handle the material in an efficient fume hood.    
   Additional Protection:       No additional protection required.    

SECTION 9: Physical and Chemical Properties
   Color and Form:       yellow-green solid    
   Molecular Weight:       507.85    
   Melting Point:       no data    
   Boiling Point:       no data    
   Vapor Pressure:       no data    
   Specific Gravity:       no data    
   Odor:       none    
   Solubility in Water:       insoluble    

SECTION 10: Stability and Reactivity
   Stability:       air and moisture-sensitive material    
   Hazardous Polymerization:       none    
   Conditions to Avoid:       exposure to oxygen, contact with strong oxidizing agents    
   Incompatibility:       strong oxidizing agents    
   Decomposition Products:       carbon dioxide, carbon monoxide, organic fumes, and neodymium oxide    

SECTION 11: Toxicological Information
   RTECS Data:       No information available in RTECS.    
   Carcinogenic Effects:       No data available    
   Mutagenic Effects:       No data available    
   Tetratogenic Effects:       No data available    

SECTION 12: Ecological Information
   Ecological Information:       No information available    

SECTION 13: Disposal Considerations
   Disposal:       Dispose of according to local, state and federal regulations.    

SECTION 14: Transportation
   Shipping Name (CFR):       Non-hazardous    
   Hazard Class (CFR):       NA    
   Additional Hazard Class (CFR):       NA    
   Packaging Group (CFR):       NA    
   UN ID Number (CFR):       NA    
   Shipping Name (IATA):       Non-hazardous    
   Hazard Class (IATA):       NA    
   Additional Hazard Class (IATA):       NA    
   Packaging Group (IATA):       NA    
   UN ID Number (IATA):       NA    

SECTION 15: Regulatory Information
   TSCA:       Not listed on the TSCA inventory.    
   SARA (Title 313):       Not reportable under SARA Title (313).    
   Second Ingredient:       none    


SECTION 16 - ADDITIONAL INFORMATION
N/A

三(四甲基环戊二烯基)铵(III) 分子结构与计算化学数据

计算化学数据

1.疏水参数计算参考值(XlogP):无

2.氢键供体数量:0

3.氢键受体数量:3

4.可旋转化学键数量:0

5.互变异构体数量:无

6.拓扑分子极性表面积0

7.重原子数量:28

8.表面电荷:0

9.复杂度:658

10.同位素原子数量:0

11.确定原子立构中心数量:0

12.不确定原子立构中心数量:3

13.确定化学键立构中心数量:0

14.不确定化学键立构中心数量:0

15.共价键单元数量:4

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产品介绍:
产品名称:三(四甲基环戊二烯基)铵(III) Cas号:164528-22-7 纯度: 包装信息:洽谈 价格:洽谈
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