氧化铑(III)五水合物

  • 基本信息
  • 制备方法及用途
  • 物化性质
  • 安全信息
  • 毒理性
  • MSDS

氧化铑(III)五水合物 基本信息

中文名称:
氧化铑(III)五水合物 
中文别名:
氧化铑(III)五水合物;
氧化铑(III)五水;
五水三氧化二铑 
英文名称:
Rhodium(III) oxide pentahydrate
英文别名:
Rhodium(III) oxide pentahydrate;
RHODIUM(III)OXIDE PENTAHYDRATE;
Rhodium (Ⅲ) oxide;
Rhodium(III)oxide,Premion99.99%(metalsbasis),Rh59%min;
Rhodium(III)oxidepentahydrate,99%;
rhodium(iii) oxide pentahydrate, premion;
RHODIUM(III) OXIDE PENTAHYDRATE: 99.9%;
Rhodium(III) oxide pentahydrate, Premion(R), 99.99% (metals basis), Rh 59% min;
Rhodium(III) oxide pentahydrate, Premion, 99.99% (metals basis), Rh 59% min 
CAS No.:
39373-27-8
分 子 式:
O3Rh2
分 子 量:
343.89
精确分子量:
343.84900
PSA:
89.52000
MDL:
MFCD00149843
EINECS:
234-846-9
风险术语:
R20/21/22; R36/37/38
分子结构式:
SDS:
查看

氧化铑(III)五水合物 制备方法及用途

制备方法

特种合金

用途简介

用途

特种合金

氧化铑(III)五水合物 物化性质

熔点:
~205 °C (dec.)
存储条件/存储方法:

 密封、阴凉、干燥保存

稳定性相关:

常规情况下不会分解,没有危险反应

其它信息:

1.       性状:蓝灰色菱形结晶。

2.       密度(g/mL,20 ºC):8.20

3.       相对蒸汽密度(g/mL,空气=1): 未确定

4.       熔点(ºC):未确定

5.       沸点(ºC):未确定

6.       沸点(ºC,16mm hg):未确定

7.       折射率:未确定

8.       闪点(ºC):未确定

9.       比旋光度(º):未确定

10.    自燃点或引燃温度(ºC): 未确定

11.    蒸气压(kPa,25ºC):未确定

12.    饱和蒸气压(kPa,60ºC): 未确定

13.    燃烧热(KJ/mol):未确定

14.    临界温度(ºC):未确定

15.    临界压力(KPa):未确定

16.    油水(辛醇/水)分配系数的对数值:未确定

17.    爆炸上限(%,V/V):未确定

18.    爆炸下限(%,V/V):未确定

19.    溶解性:不溶于水、乙醇和氢氧化钾溶液。

氧化铑(III)五水合物 安全信息

WGK_Germany:
3
德国有关水污染物质的分类清单
危险类别码:
R20/21/22:Harmful by inhalation, in contact with skin and if swallowed . R36/37/38:Irritating to eyes, respiratory system and skin .
安全说明:
S22-S24/25
危险标志:
Xn

氧化铑(III)五水合物 毒理性

生态数据:

对水是稍微有危害的不要让未稀释或大量的产品接触地下水、水道或者污水系统,若无政府许可,勿将材料排入周围环境

氧化铑(III)五水合物 MSDS


Section 1: Product Identification
   Chemical Name:       Rhodium (III) oxide pentahydrate, 99%    
   CAS Registry Number:       39373-27-8    
   Formula:       Rh2O3.5H2O    
   EINECS Number:       none    
   Chemical Family:       metal oxide    
   Synonym:       dirhodium trioxide, pentahydrate    

Section 2: Composition and Information on Ingredients
   Ingredient       CAS Number       Percent       ACGIH (TWA)       OSHA (PEL)    
   Title Compound       39373-27-8       100%       1mg/m3 (as Rh       0.1mg/m3 (as Rh    

Section 3: Hazards Identification
   Emergency Overview:       May be irritating to skin and eyes and respiratory tract.    
   Primary Routes of Exposure:       Ingestion, inhalation    
   Eye Contact:       May be a mild to severe irritant to the eyes.    
   Skin Contact:       May cause slight to mild irritation of the skin.    
   Inhalation:       Do not breath dust. Inhalation of powder may lead to irritation of the respiratory tract.    
   Ingestion:       No information available on the effects of ingestion.    
   Acute Health Affects:       May be irritating to skin, eyes, mucous membranes and respiratory tract. Do not breath dust.    
   Chronic Health Affects:       No information available on health effects of prolonged or repeated exposure.    
   NTP:       No    
   IARC:       No    
   OSHA:       No    

SECTION 4: First Aid Measures
   Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
   Eye Exposure:
   assistance in keeping their eye lids open. Get immediate medical attention.
   Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
   Skin Exposure:
   irritation persists.
   Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
   Inhalation:
   in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
   Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
   Ingestion:
   vomiting only if directed by medical personnel.

SECTION 5: Fire Fighting Measures
   Flash Point:       not applicable    
   Autoignition Temperature:       not applicable    
   Explosion Limits:       not applicable    
   Extinguishing Medium:       None. Material is non-flammable.    
   Special Fire Fighting Procedures:       No special fire fighting procedures required for this material.    
   Hazardous Combustion and       No hazardous combustion or decomposition products.    
   Decomposion Products:
   Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards.

SECTION 6: Accidental Release Measures
   Spill and Leak Procedures:       Small spills can be mixed with vermiculite or sodium carbonate and swept up.    

SECTION 7: Handling and Storage
   Handling and Storage:       Store in a tightly sealed container. Handle fine powders in a well-ventilated area.    

SECTION 8: Exposure Controls and Personal Protection
   Eye Protection:       Always wear approved safety glasses when handling a chemical substance in the laboratory.    
   Skin Protection:       Wear appropriate chemical resistant gloves and protective clothing.    
   Material may form or contain a fine dust that may become airborne during handling. If possible, handle the
   Ventilation:
   material in an efficient fume hood.
   If handling material in the form of a fine dust and ventilation is not available, a respirator should be worn. The
   Respirator:
   use of respirators requires a Respirator Protection Program to be in compliance with 29 CFR 1910.134.
   Material may form or contain a fine dust that may become airborne during handling. If possible, handle the
   Ventilation:
   material in an efficient fume hood.
   Additional Protection:       No additional protection required    

SECTION 9: Physical and Chemical Properties
   Color and Form:       yellow pwdr.    
   Molecular Weight:       253.81 (343.89)    
   Melting Point:       dec.    
   Boiling Point:       no data    
   Vapor Pressure:       not applicable    
   Specific Gravity:       no data    
   Odor:       none    
   Solubility in Water:       insoluble    

SECTION 10: Stability and Reactivity
   Stability:       air and moisture stable solid    
   Hazardous Polymerization:       no hazardous polymerization    
   Conditions to Avoid:       none    
   Incompatibility:       active metals, and phosphorous    
   Decomposition Products:       none    

SECTION 11: Toxicological Information
   RTECS Data:       No information available in the RTECS files.    
   Carcinogenic Effects:       No data available    
   Mutagenic Effects:       No data available    
   Tetratogenic Effects:       No data available    

SECTION 12: Ecological Information
   Ecological Information:       No data available    

SECTION 13: Disposal Considerations
   Disposal:       Dispose of according to local, state and federal regulations.    

SECTION 14: Transportation
   Shipping Name (CFR):       Non-hazardous    
   Hazard Class (CFR):       NA    
   Additional Hazard Class (CFR):       NA    
   Packaging Group (CFR):       NA    
   UN ID Number (CFR):       NA    
   Shipping Name (IATA):       Non-hazardous    
   Hazard Class (IATA):       NA    
   Additional Hazard Class (IATA):       NA    
   Packaging Group (IATA):       NA    
   UN ID Number (IATA):       NA    

SECTION 15: Regulatory Information
   TSCA:       Not listed in the TSCA inventory.    
   SARA (Title 313):       Title compound not listed.    
   Second Ingredient:       none    


SECTION 16 - ADDITIONAL INFORMATION
N/A

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