三甲氧基五甲基环戊二烯基钛(IV)

  • 基本信息
  • 物化性质
  • 安全信息
  • 毒理性
  • MSDS
  • 结构与计算化学

三甲氧基五甲基环戊二烯基钛(IV) 基本信息

中文名称:
三甲氧基五甲基环戊二烯基钛(IV) 
中文别名:
三甲氧基(五甲基环戊二烯)钛;
三甲氧基五甲基环戊二烯基钛(IV) 
英文名称:
Titanium,trimethoxy[(1,2,3,4,5-h)-1,2,3,4,5-pentamethyl-2,4-cyclopentadien-1-yl]-
英文别名:
carbanide,cyclopenta-1,3-diene,methanolate,titanium;
Trimethoxy(pentamethylcyclopentadienyl)titanium;
Trimethoxy(pentamethylcyclopentadienyl) titanium(IV);
Pentamethylcyclopentadienyltitanium trimethoxide;
Titanium,trimethoxy[(1,2,3,4,5-h)-1,2,3,4,5-pentamethyl-2,4-cyclopentadien-1-yl];
(Pentamethylcyclopentadienyl)trimethoxytitanium;
1,3-Cyclopentadiene,1,2,3,4,5-pentamethyl-,titanium complex 
CAS No.:
123927-75-3
分 子 式:
C13H24O3Ti
分 子 量:
276.21
精确分子量:
276.12000
PSA:
27.69000
MDL:
MFCD00269850
风险术语:
R36/37/38
安全术语:
S24/25
分子结构式:
SDS:
查看

三甲氧基五甲基环戊二烯基钛(IV) 物化性质

密度:
1.081 g/mL at 25 °C(lit.)
沸点:
285 °C(lit.)
闪点:
141 °F
折射率:
n20/D 1.554(lit.)
存储条件/存储方法:

保持贮藏器密封、储存在阴凉、干燥的地方,确保工作间有良好的通风或排气装置

稳定性相关:

如果遵照规格使用和储存则不会分解,未有已知危险反应

三甲氧基五甲基环戊二烯基钛(IV) 安全信息

WGK_Germany:
3
德国有关水污染物质的分类清单
危险类别码:
R36/37/38:Irritating to eyes, respiratory system and skin .
安全说明:
S24/25

三甲氧基五甲基环戊二烯基钛(IV) 毒理性

生态数据:

通常对水是稍微有危害的,若无政府许可,勿将材料排入周围环境。

三甲氧基五甲基环戊二烯基钛(IV) MSDS

Name: Trimethoxy(pentamethylcyclopentadienyl) titanium(IV) Material Safety Data Sheet
Synonym:
CAS: 123927-75-3
Section 1 - Chemical Product   MSDS Name:Trimethoxy(pentamethylcyclopentadienyl) titanium(IV) Material Safety Data Sheet
Synonym:

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
123927-75-3 Trimethoxy(pentamethylcyclopentadienyl unlisted
Hazard Symbols: None Listed.
Risk Phrases: None Listed.

Section 3 - HAZARDS IDENTIFICATION
  EMERGENCY OVERVIEW
Not available.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation. May be harmful if absorbed through the skin.
Ingestion:
May cause irritation of the digestive tract. May be harmful if swallowed.
Inhalation:
May cause respiratory tract irritation. May be harmful if inhaled.
Chronic:
Not available.

Section 4 - FIRST AID MEASURES
  Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Get medical aid. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately.
Notes to Physician:
Treat symptomatically and supportively.

Section 5 - FIRE FIGHTING MEASURES
  General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Will burn if involved in a fire. Combustible liquid.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
  General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Remove all sources of ignition.
Use a spark-proof tool.

Section 7 - HANDLING and STORAGE
  Handling:
Use spark-proof tools and explosion proof equipment. Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes. Handle under argon.
Storage:
Keep away from sources of ignition. Store in a cool, dry place.
Store in a tightly closed container. Store under argon.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
  Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 123927-75-3: Personal Protective Equipment Eyes: Not available.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
 
Physical State: Liquid
Color: Not available.
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 285 deg C @ 760 mmHg
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: 60 deg C ( 140.00 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density: 1.081
Molecular Formula: C13H24O3Ti
Molecular Weight: 276.21

Section 10 - STABILITY AND REACTIVITY
  Chemical Stability:
Stable.
Conditions to Avoid:
Incompatible materials, exposure to moist air or water.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide, titanium/titanium oxides.
Hazardous Polymerization: Will not occur.

Section 11 - TOXICOLOGICAL INFORMATION
  RTECS#:
CAS# 123927-75-3 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Trimethoxy(pentamethylcyclopentadienyl) titanium(IV) - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION
 

Section 13 - DISPOSAL CONSIDERATIONS
  Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION
 
IATA
Shipping Name: Flammable liquid, n.o.s.*
Hazard Class: 3
UN Number: 1993
Packing Group: III
IMO
Shipping Name: Flammable liquid, n.o.s.
Hazard Class: 3.3
UN Number: 1993
Packing Group: III
RID/ADR
No information available.

Section 15 - REGULATORY INFORMATION
 
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 123927-75-3: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 123927-75-3 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 123927-75-3 is not listed on the TSCA inventory.
It is for research and development use only.


SECTION 16 - ADDITIONAL INFORMATION
N/A

三甲氧基五甲基环戊二烯基钛(IV) 分子结构与计算化学数据

分子结构数据

1、摩尔折射率:无可用的

2、摩尔体积(cm3/mol):无可用的

3、等张比容(90.2K):无可用的

4、表面张力(dyne/cm):无可用的

5、介电常数:无可用的

6、极化率(10-24cm3):无可用的

7、单一同位素质量:276.120492 Da

8、标称质量:276 Da

9、平均质量:276.1949 Da

计算化学数据

1.疏水参数计算参考值(XlogP):无

2.氢键供体数量:0

3.氢键受体数量:9

4.可旋转化学键数量:0

5.互变异构体数量:无

6.拓扑分子极性表面积69.2

7.重原子数量:17

8.表面电荷:-9

9.复杂度:74.9

10.同位素原子数量:0

11.确定原子立构中心数量:0

12.不确定原子立构中心数量:0

13.确定化学键立构中心数量:0

14.不确定化学键立构中心数量:0

15.共价键单元数量:10

推荐供应商更多供应商>>

湖北万得化工有限公司

产品介绍:
产品名称:五甲基环戊二烯基钽三甲基醇盐 Cas号:123927-75-3 纯度:99% 包装信息:1t吨袋,200kg镀锌铁桶/塑料桶,25kg纸板桶/编织袋/塑料桶,10kg铝听/纸箱,1kg铝箔袋/氟化瓶 价格:1.0元 - 1,000.0元
联系方式:
联系人:王念 电话:027-59210159 手机:15172311821

湖北齐飞医药化工有限公司

产品介绍:
产品名称:三甲氧基(五甲基环戊二烯)钛 Cas号:123927-75-3 纯度:99% 包装信息:25kg纸板桶/编织袋/塑料桶 价格:25.0元
联系方式:
联系人:汪经理 电话:027-59322506 手机:18071128683

湖北实顺生物科技有限公司

产品介绍:
产品名称:三甲氧基(五甲基环戊二烯)钛 Cas号:123927-75-3 纯度:99% 包装信息:25kg纸板桶/编织袋/塑料桶 价格:25.0元
联系方式:
联系人:张经理 电话:027-59223025 手机:15172526927

湖北信康医药化工有限公司

产品介绍:
产品名称:三甲氧基五甲基环戊二烯基钛(IV) Cas号:123927-75-3 纯度:99% 包装信息:25kg纸板桶/编织袋/塑料桶 价格:25.0元
联系方式:
联系人:张欢 电话:027-59308705 手机:18827031272

湖北永阔科技有限公司

产品介绍:
产品名称:三甲氧基(五甲基环戊二烯)钛 Cas号:123927-75-3 纯度:99% 包装信息:25kg纸板桶/编织袋/塑料桶 价格:25.0元
联系方式:
联系人:徐 电话:027-59223108 手机:15107166787

天门恒昌化工有限公司

产品介绍:
产品名称:三甲氧基(五甲基环戊二烯)钛 Cas号:123927-75-3 纯度:99% 包装信息:25kg纸板桶/编织袋/塑料桶 价格:25.0元
联系方式:
联系人:黄经理 电话:027-59322316 手机:15827039378

湖北广奥生物科技有限公司

产品介绍:
产品名称:五甲基环戊二烯基钽三甲基醇盐 Cas号:123927-75-3 纯度:99% 包装信息:1t吨袋,200kg镀锌铁桶/塑料桶,25kg纸板桶/编织袋/塑料桶,10kg铝听/纸箱,1kg铝箔袋/氟化瓶 价格:1.0元 - 1,000.0元
联系方式:
联系人:孙经理 电话:027-59223056 手机:15271829679

湖北巨胜科技有限公司

产品介绍:
产品名称:三甲氧基五甲基环戊二烯基钛(IV) Cas号:123927-75-3 纯度:99% 包装信息:25kg纸板桶/编织袋/塑料桶 价格:25.0元
联系方式:
联系人:孙敏 电话:027-59599240 手机:18702754003

湖北摆渡化学有限公司

产品介绍:
产品名称:三甲氧基(五甲基环戊二烯)钛 Cas号:123927-75-3 纯度:99% 包装信息:25kg 价格:1.0元
联系方式:
联系人:邹经理 电话:027-59223020 手机:18871490324

湖北鑫红利化工有限公司

产品介绍:
产品名称:三甲氧基(五甲基环戊二烯)钛 Cas号:123927-75-3 纯度:99% 包装信息:1kg铝箔袋/氟化瓶,10kg铝听/纸箱,25kg纸板桶/编织袋/塑料桶,200kg镀锌铁桶/塑料桶,1t吨袋 价格:1.0元 - 1,000.0元
联系方式:
联系人:周女士 电话:027-59503710 手机:18871490254